| Abstract: | Soil-pore water sampling by suction lysimeters monitors the fate of soil contaminants as a function of depth and time. However, sampling campaigns must be planned to most effectively monitor the migration of contaminants with a minimum expenditure of resources. The vertical migration of pesticides was studied at two sites treated with systemic s-triazine herbicides and equipped with suction lysimeters. The measured concentrations were compared with those calculated by a simulation model. This modeling was based on the processes that control the transport and fate of pesticide within the soil. The usefulness of such a tool was demonstrated by the good approximation obtained for pesticide concentrations and arrival times. Moreover, the significant spatial variability of concentrations observed justifies the use of a stochastic approach in modeling that takes into account the spatial variability of soil parameters. Also, the rapid transformation of herbicides observed in unsaturated soil zones demonstrates the importance of taking into account the sum of the toxic residues when evaluating the fate of s-triazines in soil. |
