Dispersive Liquid–Liquid Microextraction for Preconcentration and Determination of Nickel in Water |
| |
| Authors: | Valfredo A Lemos Emanuel V dos Santos Vieira Eldevan dos Santos Silva Liz O dos Santos |
| |
| Institution: | Universidade Estadual do Sudoeste da Bahia, Laboratório de Química Analítica (LQA), Jequié, Bahia, Brazil |
| |
| Abstract: | A method for the determination of nickel in water was developed. The procedure involves preconcentration of nickel by using dispersive liquid–liquid microextraction. The Ni(II) ions were extracted in chloroform in the form of complex with the reagent 2‐(2′‐benzothiazolylazo)‐p‐cresol. Ethanol was used as the disperser solvent. After injection of the extracting mixture in a solution of nickel, a cloudy mixture was observed. A quick centrifugation induces phase separation and thus the settling of rich phase. The nickel content in the rich phase is measured by flame atomic absorption spectrometry. Under optimal conditions, the limit of detection and quantification obtained were 1.4 and 4.7 µg L?1, respectively. Some parameters used to characterize preconcentration systems, such as enrichment factor and consumption index were calculated and resulted in 29 and 0.34 mL, respectively. After optimization of variables and determination of analytical characteristics, the method was used for the analysis of certified reference materials (BCR‐713: wastewater, effluent and BCR‐414: plankton) and real water samples. |
| |
| Keywords: | BTAC Complexation Flame atomic absorption spectrometry (FAAS) Trace concentrations |
|
|
