Ionic Liquid Modified Resin for the Adsorptive Removal of Dibutyl Phthalate: Equilibrium,Kinetic, and Thermodynamic Studies |
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| Authors: | Umair A Qureshi Amber R Solangi Saima Q Memon Syed I H Taqvi Najma Memon |
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| Institution: | 1. National Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, Pakistan;2. Institute of Advanced Research Studies in Chemical Sciences, University of Sindh, Jamshoro, Pakistan;3. Govt. College Kali Mori, Hyderabad, Pakistan |
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| Abstract: | This study evaluated the adsorptive properties of dibutyl phthalate (DBP) on room temperature ionic liquid (RTIL) modified XAD‐4 resin. The modified RTIL‐XAD 4 sorbent was characterized by FTIR. Effect of varying experimental conditions such as pH, contact time, temperature, shaking speed, concentrations, and interfering species were investigated by batch adsorption experiments. Adsorption was found to be most favorable at pH 6 within 30 min. Experimental data were evaluated in terms of kinetic, equilibrium, and thermodynamic modeling. Kinetics of the sorption was found to follow pseudo second order rate equation whereas Freundlich and D–R isotherms were the most suitable models to explain sorption phenomenon. Thermodynamically sorption was endothermic, irreversible, and spontaneous in nature. |
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| Keywords: | Adsorption DBP Ionic liquid Purification Wastewater treatment |
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