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东太湖沉积物中多环芳烃-菲系列化合物的来源探讨
引用本文:瞿文川,王苏民,吴瑞金,张平中,崔明中.东太湖沉积物中多环芳烃-菲系列化合物的来源探讨[J].湖泊科学,2001,13(1):9-14.
作者姓名:瞿文川  王苏民  吴瑞金  张平中  崔明中
作者单位:1. 中国科学院南京地理与湖泊研究所,南京210008
2. 中国科学院兰州地质研究所,兰州 730000
基金项目:中国科学院重大项目! (KZ95 1-B1- 2 0 5,KZ95 1-A1- 40 2 ),南京地理与湖泊研究所所长基金
摘    要:本文用索氏抽取法提取了东太湖的沉积物和水生植物中的可溶性有机质,用不同极性溶剂在硅胶/氧化铝柱上分离了饱和烃、芳烃、酮馏分,利用GC-MS至芳烃组分进行了鉴定分析,并对其中重要多环芳烃-菲系列化合物的来源进行了探讨。

关 键 词:太湖  多径芳烃  菲系列化合物  来源识别  湖泊沉积物  水生植物  索氏抽取法
收稿时间:2000/2/24 0:00:00
修稿时间:2000/10/15 0:00:00

Determination and Sources Recognition of Phenanthrene Series in the Sediments of East Taihu Lake, China
QU Wenchuan,WANG Sumin,WU Ruijin,ZHANG Ping zhong and CUI Mingzhong.Determination and Sources Recognition of Phenanthrene Series in the Sediments of East Taihu Lake, China[J].Journal of Lake Science,2001,13(1):9-14.
Authors:QU Wenchuan  WANG Sumin  WU Ruijin  ZHANG Ping zhong and CUI Mingzhong
Institution:Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008, P. R. China,Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008, P. R. China,Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, Nanjing 210008, P. R. China,Lanzhou Institute of Geology, Chinese Academy of Sciences, Lanzhou 730000, P. R. China and Lanzhou Institute of Geology, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
Abstract:There has been a growing concern in recent years regarding possible harmful effects to man and other living organisms of pollutant organic chemicals released into the environment as a consequence of human activities. Polycyclic aromatic hydrocarbons (PAHs) are one of the more significant classes of pollutants, which give rise to this concern. This concern arises primarily from the fact that some PAHs generated and released to the environment by human activities have shown to be carcinogenic to mammals. Many researches have been done about the properties of PAHs. PAHs of different molecular weights or structures vary substantially in their behavior and distribution in the environment and their effects on biological systems. PAHs can be formed mainly in three ways: high temperature pyrolysis of organic materials, low to moderate temperature diagensis of sedimentary organic material to form fossil fuels, and direct biogenesis by microbes and plants. In this paper, the extractable lipids were isolated using Soxhlet extraction method in the East Taihu Lake sediment, the extracts were fractionated on an activated SiO 2/Al 2O 3 column. The aromatic compounds were washed in benzene. Phenanthrene series, one group of important polycyclic aromatic hydrocarbons were analyzed and identified by the GC-MS instrument. The sources of Phenanthrene in Taihu Lake sediment were discussed. Phenanthrene series were also found from the aquatic plants with similar composition pattern with that in the East Taihu Lake sediment. This is the first time that aquatic plants have been singled out as the major source of phenanthrene series in the East Taihu Lake sediments.
Keywords:Taihu Lake  sediment  PAH  phenanthrene  sources recognition
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