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Porphyry copper and tin-bearing porphyries a discussion of genetic models
Authors:Jorge Oyarzun M  Jose Frutos J
Institution:IRITUN. Universidad del Norte, Antofagasta Chile;Departamento Geología, Universidad del Norte, Antofagasta Chile
Abstract:The paper briefly describes the characteristics of the Chilean porphyry copper deposits, emphasizing the volcanic characteristics observed in the youngest ore bodies. Mention is made of the polymetallic ore bodies that are associated with rhyolitic porphyries intruding Jurassic sedimentary formations in the north of Chile, and the similarities and differences between the Chilean porphyry coppers and the Bolivian tin-bearing porphyries are pointed out.The models proposed by Sillitoe (1972), Brousse and Oyarzún (1971), and Mitchell and Garson (1972), are discussed and a new model is proposed agreeing with that of Mitchell and Garson for the genesis of the tin-bearing porphyries (the transportation of Sn as volatile halogenide by F liberated in the Benioff zone), but suggesting different generating mechanism for the porphyry coppers and polymetallic deposits related with porphyries. This mechanism, as a part of the global tectonic model, is based on the separation at depth of hydrogen sulphide from pyrite and water introduced with the upper layers of the lithospheric plate. The ascending migration of H2S to high levels in the crust would be responsible for the porphyry copper mineralization by segregating sulphides of Fe, Cu, Mo and other sulphophile metals contained in the calc-alkaline magmas, brines, or sedimentary-volcanic formations intruded by the porphyries. The excess of H2S would give rise to the formation of sulphur deposits normally present in the volcanic belt situated along the same line but at a higher level than those of the emplacement of porphyry coppers.The generation of copper and tin-bearing porphyries would be a consequence of the upward migration of volatile substances from different depths in the subduction zone, which explain its different emplacement with regards to the continental margins.
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