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Metals in Sediments of the Upper Laguna Madre
Authors:Virender K Sharma  Kurtis B Rhudy  Robert Koening  Felipe G Vazquez
Institution:

a Department of Chemistry, Texas A&M University – Corpus Christi, 6300 Ocean Drive, Corpus Christi, TX 78412, USA

b Instituto de Ciencias del Mar y Limnologia, UNAM, Cd., Universitaria, D.F. Apartado Postal 70-305, C.P. 04510, Mexico

Abstract:The Laguna Madre system is the largest hypersaline coastal basin in the United States. Surface sediments from 22 Upper Laguna Madre (ULM) sites were analyzed for grain size and metals (Cd, Cu, Ba, Cr, Mn, Ni, Pb, V, Zn, Fe, and Al) to assess the extent of contamination in the area. Sediments were found to consist mainly of sand texture. Clay and silts were minor constituents (<10%) of the sediments. Anomalies in metal concentrations were found at some sites and were related to probable sources, i.e., recreational and industrial activities. Concentrations of metals were normalized to grain size, Al, and Fe to distinguish natural and anthropogenic sources. Most metals showed positive correlations (p < 0.001) with Fe and Al, suggesting a natural variability of metal concentrations in sediments. Concentrations of metals, except Cd and Pb, at most sites were found to be below threshold concentrations thought to produce toxic effects in marine and estuarine organisms.
Keywords:Laguna Madre  metals  sediments  contamination
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