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Distribution of synthetic organotins and total tin levels in Mytilus galloprovincialis along the Portuguese coast
Authors:Ana Sousa  Tokutaka Ikemoto  Carlos Barroso
Institution:a CESAM and Department of Biology, University of Aveiro, 3810-193 Aveiro, Portugal
b Center for Marine Environmental Studies (CMES), Ehime University, Bunkyo-cho 2-5, Matsuyama 790-8577, Japan
Abstract:Despite the huge amount of literature available on butyltins (BuTs), few studies addressed the environmental levels of phenyltins (PhTs), octyltins (OcTs) and total tin (SnT) in environmental samples. In 2006 a mussel watch survey was developed for the Portuguese coast (total of 29 sampling sites) in order to describe the concentrations of BuTs , PhTs, OcTs and SnT in the whole tissues of Mytilus galloprovincialis (Lamarck, 1819). BuTs were detected in all analyzed samples accounting, in average, for 98.6% of total organotins (∑OTs = BuTs + PhTs + OcTs), and presented highest values in the vicinity of harbors. Tributyltin (TBT) was the dominant butyltin, representing, in average, 62% of ∑BuTs (∑BuTs = TBT + DBT + MBT) suggesting that fresh inputs of TBT are still occurring in the Portuguese coast, particularly near harbors. The contribution of organotin compounds derived from antifouling paints to the total tin levels in M. galloprovincialis is discussed.
Keywords:Tributyltin  Total tin  Mytilus galloprovincialis  Portuguese coast
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