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Identifying outliers and assessing the accuracy of amino acid racemization measurements for geochronology: II. Data screening
Authors:Matthew A Kosnik  Darrell S Kaufman  
Institution:aSchool of Marine & Tropical Biology, James Cook University, Townsville, Qld 4811, Australia;bDepartment of Geology, Northern Arizona University, Flagstaff, AZ 86011-4099, USA
Abstract:Amino acid racemization (AAR) is a cost-effective method for dating the large numbers of specimens required for time-averaging studies. Because the aim of time-averaging studies is to determine the structure of the age distribution, any data screening must be done cautiously and systematically. Methods to quantitatively assess the quality of AAR data and to identify aberrant specimens are under-developed. Here we examine a variety of screening criteria for identifying outliers and determining the suitability of specimens for numerical dating including: high serine concentrations (modern contamination), covariance of aspartic acid (Asp) and glutamic acid (Glu) concentrations (diagenetic influences), replication of measurements (specimen heterogeneity), and the relation between Asp and Glu d/l values (internal consistency). This study is based on AAR analyses of 481 late Holocene shells of four molluscan taxa (Ethalia, Natica, Tellina, and Turbo) collected from shallow sediment cores from the central Great Barrier Reef. Different outliers are flagged by the different screening criteria, and 6% of specimens were found to be unsuitable for time-averaging analyses based on screening the raw AAR data. We recommend a hybrid approach for identifying outliers and specimens for numerical dating.
Keywords:Mollusca  Amino acid geochronology  Holocene  Carbonate sediments  Time-averaging  Great Barrier Reef  Amino acid racemization
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