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Nitrous oxide emissions from fertilized and unfertilized soils in a subtropical region (Andalusia,Spain)
Authors:F Slemr  R Conrad  W Seiler
Institution:(1) Max-Planck-Institut für Chemie, Saarstrasse 23, D-6500 Mainz, F.R.G.
Abstract:Field measurements of N2O emission rates were carried out from August until October 1982 in a subtropical region in Europe, i.e. in Andalusia, Spain. The measurements were performed by using an automatic sampling and analysis technique allowing the semi-continuous determination of N2O emission rates. The N2O emission rates were positively correlated to the soil surface temperature and exhibited a diurnal rhythm with maximum rates in the afternoon and minimum rates in the early morning with average values of 1 mgrg N2O–N/m2/h for the grass lawn and 15 mgrg N2O–N/m2/h for cultivated land. Application of urea and ammonium nitrate resulted in elevated N2O emission rates when compared to the unfertilized control. The loss of fertilizer-nitrogen as N2O was 0.18% for urea and 0.04% for NH4NO3 which compares very well with data obtained in a temperate climate (Germany). The total source strength of fertilizer-derived N2O is estimated to be 0.01–2.2 Tg N2O–N per year. The N2O flux from unfertilized natural soils may be as high as 4.5 Tg N2O–N, indicating that the N2O emission from soils contributes significantly to the global N2O budget.
Keywords:N2O emission  nitrogen fertilizer  soil  subtropics  atmospheric budget
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