A Condensed Gas-Phase Chemical Model and Its Application |
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| Authors: | Wang Tijian Sun Zhaobo and Li Zongkai |
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| Institution: | Department of Atmospheric Sciences, Nanjing University, Nanjing 210093,Nanjing Institute of Meteorology, Nanjing 210044,Department of Atmospheric Sciences, Nanjing University, Nanjing 210093 |
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| Abstract: | Using the "lumped mechanism" and "counting species" methods, we developed a condensed gas-phasechemical model based on a simplified one. The modified quasi-steady-state approximation (QSSA) schemeand the error redistribution mass conservation technique are adopted to solve the atmospheric chemistry kinetic equations. Results show that the condensed model can well simulate concentration variations of gasspecies such as SO2, NOx, O3, H2O2 and conversion rates of SO2 and NOx transformation to H2SO4 andHNO3. These results are in good agreement with those from the simplified model. The conversion rates ofSO2 and NOx under different initial concentrations and meteorological conditions are computed, and theresults can be directly applied to regional acid deposition model. |
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| Keywords: | Gas-phase chemistry Conversion rate |
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