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胶州湾及其邻近河流中壬基酚等有机污染物的分布特征
引用本文:李正炎,傅明珠,卫东.胶州湾及其邻近河流中壬基酚等有机污染物的分布特征[J].海洋与湖沼,2008,39(6):599-603.
作者姓名:李正炎  傅明珠  卫东
作者单位:中国海洋大学海洋环境与生态教育部重点实验室,青岛,266100
基金项目:国家自然科学基金 , 山东省环境保护科技项目  
摘    要:为分析青岛胶州湾及其邻近河流中的壬基酚(NP)及其短链氧乙烯醚母体化合物、壬基酚单氧乙烯醚(NP1EO)和壬基酚二氧乙烯醚(NP2EO)的污染状况和分布特征,在研究区域内设置了17个站位分别采集了海水和沉积物样品,样品经萃取、浓缩、净化后采用气质联用仪测定各污染物的浓度。胶州湾水体中的NP、NP1EO和NP2EO的浓度分别为20.2-268.7、11.2-200.4和4.8-32.5ng/L。胶州湾沉积物中上述3种污染物的浓度分别为3.6-299.3、3.8-25.2和4.9-103.2ng/g。胶州湾邻近河流中的污染物浓度远远高于湾内,其中墨水河的污染最严重,水体和沉积物中NP的浓度分别达到28656ng/L和31704ng/g。与世界其他海湾NP等污染物的浓度相比,胶州湾属于严重污染地区之一,已经超出了其生物效应临界浓度。研究区域内50%的站位中NP浓度已经超过导致扇贝苗死亡的临界浓度,10%的站位已经超过引起雄性鱼类雌性化的临界浓度。

关 键 词:壬基酚  壬基酚聚氧乙烯醚  内分泌干扰物  胶州湾
收稿时间:2006/1/12 0:00:00
修稿时间:2007/3/19 0:00:00

DISTRIBUTION OF NONYLPHENOL IN JIAOZHOU BAY AND ITS ADJACENT RIVERS
LI Zheng-Yan,FU Ming-Zhu and WEI Dong.DISTRIBUTION OF NONYLPHENOL IN JIAOZHOU BAY AND ITS ADJACENT RIVERS[J].Oceanologia Et Limnologia Sinica,2008,39(6):599-603.
Authors:LI Zheng-Yan  FU Ming-Zhu and WEI Dong
Institution:Key Lab of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao, 266100;Key Lab of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao, 266100;Key Lab of Marine Environmental Science and Ecology, Ministry of Education, Ocean University of China, Qingdao, 266100
Abstract:Pollution and distribution of nonylphenol (NP), nonylphenol monoethoxylate (NPIEO) and nonylphenol diethoxylate (NPZEO) in Jiaozhou Bay and its adjacent rivers were studied. Water and sediment samples were collected from 17 stations in the study area. The samples were extracted, concentrated and purified. Each pollutant species was quantified with GC-MS. The concentrations of NP, NPIEO, and NPZEO in surface waters of Jiaozhou Bay ranged 20.2-268.7, 11.2-200.4 and 4.8-232.5 ng/L, and in the sediments 3.6-299.3, 3.8-25.2 and 4.9-103.2 ng/g, respectively. The contamination in the adjacent rivers was much more serious than inside the bay. Moshui River is most seriously polluted reaching nonylphenol concentrations of 28656 ng/L and 31704 ng/g in water and sediment, respectively. Compared with other bays in the world, Jiaozhou Bay is one of the most polluted areas, with the concentrations exceeding the threshold biological effect level, building potential risks on local organisms.
Keywords:Nonylphenol  Nonylphenol ethoxylates  Endocrine disrupting chemicals  Jiaozhou Bay
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