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黄、东海海域溶解无解机砷分布特征与化学形态
引用本文:吴斌,宋金明,李学刚.黄、东海海域溶解无解机砷分布特征与化学形态[J].海洋学报(英文版),2015,34(6):12-20.
作者姓名:吴斌  宋金明  李学刚
作者单位:中国科学院海洋研究所 海洋生态与环境科学重点实验室 青岛, 266071;国家海洋局第一海洋研究所 海洋沉积与环境地质重点实验室 青岛, 266061,中国科学院海洋研究所 海洋生态与环境科学重点实验室 青岛, 266071,中国科学院海洋研究所 海洋生态与环境科学重点实验室 青岛, 266071
基金项目:The Strategic Priority Research Program of the Chinese Academy of Sciences under contract No. XDA11020102; the National Natural Science Foundation of China under contract Nos 41306055 and U1406403.
摘    要:Distribution and chemical speciation of dissolved inorganic arsenic were examined in Yellow Sea and East China Sea. Results demonstrated that: (1) both As(III) and As(V) were detected, with As(V) domin...

关 键 词:溶解无机砷  分布  形态  黄海  东海
收稿时间:2014/2/21 0:00:00
修稿时间:7/4/2014 12:00:00 AM

Distribution and chemical speciation of dissolved inorganic arsenic in the Yellow Sea and East China Sea
WU Bin,SONG Jinming and LI Xuegang.Distribution and chemical speciation of dissolved inorganic arsenic in the Yellow Sea and East China Sea[J].Acta Oceanologica Sinica,2015,34(6):12-20.
Authors:WU Bin  SONG Jinming and LI Xuegang
Institution:1.Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China;Key Laboratory of Marine Sedimentology and Environmental Geology, First Institute of Oceanography, State Oceanic Administration, Qingdao 266061, China2.Key Laboratory of Marine Ecology and Environmental Sciences, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China
Abstract:Distribution and chemical speciation of dissolved inorganic arsenic were examined in Yellow Sea and East China Sea. Results demonstrated that: (1) both As(III) and As(V) were detected, with As(V) dominated at 40% stations of surface water and 51% stations of bottom water; (2) influenced by the exchange of fresh and sea water, the type of surface sediment and the transport of various water masses, large values in surface water were observed along the coastal region and in the same latitude of Changjiang River Estuary and Hangzhou Bay, and in bottom water found in the southern area where the Taiwan Warm Current and Kuroshio Current influenced; (3) As(III) behaved non-conservatively in Changjiang River Estuary. Man-derived inputs cause substantial positive deviation from the theoretical dilution. The negative correlation of As(V) to salinity in surface water suggested that it behaved conservatively during the transportation along Changjiang River Estuary. While, the occurrence of As(V) up to the linear fit in bottom water indicated the eventual transfer from dissolved phase to particulate phase, which was impossible to be determined without the knowledge of arsenic level and speciation in suspended particulate matter. Further study is needed on the arsenic source/sink relationships based on the distribution profiles.
Keywords:dissolved inorganic arsenic  distribution  speciation  Yellow Sea  East China Sea
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