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Distribution of moretene, sterere, fernene, hopene and dienoic carboxylic acid in marine sediments in sea area of the Southern Ocean
作者姓名:Jiang Shanchun  Tang Yunqian
作者单位:Jiang Shanchun and Tang Yunqian Institute of Geochemistry,Guangzhou Branch,Academia Sinica,Guangzhou 510640,China Second Institute of Oceanography,State Oceanic Administration,Hangzhou 310012,China
基金项目:This project is supported by National Laboratory of Organic Geochemistry China
摘    要:The soluble organic matters were extracted from marine sediments in the sea area of Southern Ocean by using organic solvents. The hydrocarbon and carboxylic acid fractions were separated with the thin layer chromatography. The organic compounds of 170(H), 21α(H)- bishomomoretene, cholest - 5 - ene, 24 - methyl - cholestene, 24 - ethylcholestene, hop-17(21)-ene, neohop - 13(18)-ene, fern-8-ene, fern-7-ene, 170(H), 210 (H) - hop - 22(29)-ene (diplotene), steranes, β, β-hopanes C29 -C31 and unsaturated carboxylic acids C18:2Δ9.12 , C18:1Δ9,C18:1Δ11 , have been identi-fied in the hydrocarbon and carboxylic acid fractions by means of gas chromatography and gas chromatography - mass spec-trometry - data system. The distributions of 3, a - bishomomoretene, β,β- hopene and β,β- hopane are characteristic of immature organic matter. The sterane, C29 20S/20R epimer ratio 0. 6 indicate that the organic matter had experienced a thermal evolution in the early sedimentation. The unsaturated fatty acids espec

关 键 词:Lipids  diplotene  moretene  sterene  fernene  dienoic  cacboxylic  acid
收稿时间:1992/2/26 0:00:00
修稿时间:1992/8/30 0:00:00

Distribution of moretene, sterere, fernene, hopene and dienoic carboxylic acid in marine sediments in sea area of the Southern Ocean
Jiang Shanchun,Tang Yunqian.Distribution of moretene, sterere, fernene, hopene and dienoic carboxylic acid in marine sediments in sea area of the Southern Ocean[J].Acta Oceanologica Sinica,1993,12(2):237-247.
Authors:Jiang Shanchun and Tang Yunqian
Institution:1.Institute of Geochemistry, Guangzhou Branch, Academia Sinica, Guangzhou 510640, China2.Second Institute of Oceanography, State Oceanic Administration, Hangzhou 310012, China
Abstract:The soluble organic matters were extracted from marine sediments in the sea area of Southern Ocean by using organic solvents. The hydrocarbon and carboxylic acid fractions were separated with the thin layer chromatography. The organic compounds of 170(H), 21α(H)-bishomomoretene, cholest-5-ene, 24-methyl-cholestene, 24-ethylcholestene, hop-17(21)-ene, neohop-13(18)-ene, fern-8-ene, fern-7-ene, 170(H), 210 (H)-hop-22(29)-ene (diplotene), steranes, β, β-hopanes C29-C31 and unsaturated carboxylic acids C18:2Δ9.12, C18:1Δ9,C18:1Δ11, have been identi-fied in the hydrocarbon and carboxylic acid fractions by means of gas chromatography and gas chromatography-mass spec-trometry-data system. The distributions of 3, a-bishomomoretene, β,β-hopene and β,β-hopane are characteristic of immature organic matter. The sterane, C29 20S/20R epimer ratio 0.6 indicate that the organic matter had experienced a thermal evolution in the early sedimentation. The unsaturated fatty acids especially dienoic acids and fernene compounds indicare not only the origin from autochthonous bacteria but also the reducing environment in the Southern Ocean.
Keywords:Lipids  diplotene  moretene  sterene  fernene  dienoic cacboxylic acid
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