| Colorimetric determination of nanomolar concentrations of silicate in natural waters after liquid-liquid extraction using methyl isobutyl ketone |
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| 作者姓名： | REN Jingling MI Tiezhu DOU Weiwei LIU Sumei ZHANG Jing |
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| 作者单位： | REN Jingling（Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education,Ocean University of China,Qingdao 266100,China） ;
MI Tiezhu（College of Environmental Science and Engineering,Ocean University of China,Qingdao 266100,China） ;
DOU Weiwei（Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education,Ocean University of China,Qingdao 266100,China） ;
LIU Sumei（Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education,Ocean University of China,Qingdao 266100,China） ;
ZHANG Jing（Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education,Ocean University of China,Qingdao 266100,China;State Key Laboratory of Estuarine and Coastal Research,East China Normal University,Shanghai 200062,China） ; |
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| 基金项目： | The National Science Foundation of China under contract No.40606028 and the Special Fund from the National Key Basic Research Program of China under contract No.2006CB400601. |
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| 摘 要： | A sensitive solvent extraction method for the determination of nonamolar concentrations of silicate in natural waters is developed. According to the traditional aqueous silicate method, silicomolybdenum blue formed by the reaction between silicate and ammoni- um molydate and reduced by metol-sulfite reagent is extracted by methyl isobutyl ketone. The absorbance can be enhanced substantially up to 10-folds. The detection limit of silicate is 8 nmol/dm^3 , which is one tenth smaller than the traditional method, with the precision of 4.0% at a silicate level of 50 nmol/dm^3 and 3.2% at a silicate level of 6 μmol/dm^3. Comparing the calibration curves in the distilled water and seawater, it can be seen that the salt effect also exists in the extraction method. However, the salt effect is a linear function of the salinity and can be corrected by simple calibration. The proposed method is successfully applied to the determination of silicate in natural waters. Natural concentrations of arsenate, arsenite and phosphate cause negligible interference.
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| 关 键 词： | 硅酸盐 比色测定 液-液萃取 甲基异丁基酮 |
| 收稿时间： | 2006/7/12 0:00:00 |
| 修稿时间： | 2007/1/12 0:00:00 |
Colorimetric determination of nanomolar concentrations of silicate in natural waters after liquid-liquid extraction using methyl isobutyl ketone |
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| REN Jingling,MI Tiezhu,DOU Weiwei,LIU Sumei,ZHANG Jing.Colorimetric determination of nanomolar concentrations of silicate in natural waters after liquid-liquid extraction using methyl isobutyl ketone[J].Acta Oceanologica Sinica,2008,27(1):137-146. |
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| Authors: | REN Jingling MI Tiezhu DOU Weiwei LIU Sumei and ZHANG Jing |
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| Institution: | 1.Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education, Ocean University of China, Qingdao 266100, China2.College of Environmental Science and Engineering, Ocean University of China, Qingdao 266100, China3.Key Laboratory of Marine Chemistry Theory and Technology of Ministry of Education, Ocean University of China, Qingdao 266100, China;State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062, China |
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| Abstract: | A sensitive solvent extraction method for the determination of nonamolar concentrations of silicate in natural waters is developed. According to the traditional aqueous silicate method,silicomolybdenum blue formed by the reaction between silicate and ammoni- um molydate and reduced by metel-sulfite reagent is extracted by methyl isobutyl ketone.The abserbance can be enhanced sub- stantially up to 10-folds.The detection limit of silicate is 8 nmoL/dm3,which is one tenth smaller than the traditional method, with the precision of 4.0% at a silicate level of 50 nmol/dm3 and 3.2% at a silicate level of 6 μmol/dm3.Comparing the calibra- tion curves in the distilled water and seawater,it can be seen that the salt effect also exists in the extraction method.However,the salt effect is a linear function of the salinity and can be corrected by simple calibration.The proposed method is successfully ap- plied to the determination of silicate in natural waters.Natural concentrations of arsenate,arsenite and phosphate cause negligible interference. |
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| Keywords: | silicate colorimetric determination liquid-liquid extraction methyl isebutyl ketone |
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