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Hydrogen peroxide concentrations in the Peru upwelling area
Authors:Rod G Zika  Eric S Saltzman  William J Cooper
Institution:Marine and Atmospheric Chemistry Division, Rosenstiel School of Marine and Atmospheric Science, University of Miami, 4600 Rickenbacker Causeway, Miami, FL 33149 U.S.A.
Abstract:The concentration of hydrogen peroxide was measured in waters off the coast of Peru during June and July 1983. The study period coincided with the end of the 1982/83 El Niño and the onset of coastal upwelling. Depth profiles of hydrogen peroxide concentration exhibit surface maxima and decrease with depth to the base of the mixed layer. Surface peroxide concentrations ranged from 0.8 to 5 × 10?8 M. Below the mixed layer hydrogen peroxide was below the detection limit (5 × 10?9 M). Diel variations were observed, with surface peroxide levels increasing during the day and decreasing at night. The nearshore station exhibited lower hydrogen peroxide concentrations than offshore stations, a reversal of the trend found in other coastal regions. This is attributed to the lack of coastal vegetation and runoff, and to active coastal upwelling of deeper water with low hydrogen peroxide concentrations.
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