| 对合成2,4,6-三异丙基-1,3,5-三氧杂环已烷的改进(英文) |
| |
| 引用本文： | 钱佐国,刘翔,张颖,孙明昆.对合成2,4,6-三异丙基-1,3,5-三氧杂环已烷的改进(英文)[J].中国海洋大学学报(自然科学版),1992(3). |
| |
| 作者姓名： | 钱佐国 刘翔 张颖 孙明昆 |
| |
| 作者单位： | 青岛海洋大学海洋化学系
(钱佐国，刘翔，张颖)，青岛海洋大学海洋化学系(孙明昆) |
| |
| 摘 要： | 报道一种以环已烷为溶剂由异丁醛经环化三聚合成2,4,6-三异丙基-1,3,5三氧杂环已烷的方法。与苯作溶剂的方法相比,其优点是产物的收率高、毒性低。同时提出一种异丁醛环化三聚的反应机理。
|
| 关 键 词： | 2 4 6-三异丙基-1 3 5-三氧杂环已烷 环已烷 环化三聚 反应机理 |
AN IMPROVEMENT ON SYNTHESIS OF 2, 4, 6-TRIISOPROPYL-1, 3, 5-TRIOXANE |
| |
| Qiao Zuoguo Liu Xiang Zhang Ying Sun Mingkun.AN IMPROVEMENT ON SYNTHESIS OF 2, 4, 6-TRIISOPROPYL-1, 3, 5-TRIOXANE[J].Periodical of Ocean University of China,1992(3). |
| |
| Authors: | Qiao Zuoguo Liu Xiang Zhang Ying Sun Mingkun |
| |
| Institution: | Department of Marine Chemistry |
| |
| Abstract: | This paper reports a procedure in which cyclobexane was used as solvent for the synthesis of 2,4,6-triisopropyl-1,3 5-trioxanc from isobutyraldehyde by cyclic trimerization.It has the advantage of higher yield and lower toxicity than those when benzene was used as solvent A reaction mechanism was also suggested in this paper. |
| |
| Keywords: | 2 4 6-triisopropyl-1 3 5-trioxane cyclohexane cyclic trimerzation reaction mechanism |
| 本文献已被 CNKI 等数据库收录！ |
|
