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日照近岸海域表层沉积物中多环芳烃(PAHs)来源的识别和解析
引用本文:郎印海,薛荔栋,刘爱霞,刘洁.日照近岸海域表层沉积物中多环芳烃(PAHs)来源的识别和解析[J].中国海洋大学学报(自然科学版),2009,39(3).
作者姓名:郎印海  薛荔栋  刘爱霞  刘洁
作者单位:中国海洋大学环境科学与工程学院海洋环境与生态教育部重点实验室,山东,青岛,266100
摘    要:利用GC-MS测定日照近岸海域表层沉积物中多环芳烃(PAHs)浓度,采用低环与中高环PAHs的相对丰度以及同分异构体的比值方法,初步解析出表层沉积物中PAHs主要来自于燃煤(工业燃煤、民用燃煤)、燃油(柴油燃烧、汽油燃烧)、焦化、柴油泄漏、木材燃烧等污染源.通过查阅文献获取上述污染源相关源成分谱,应用降解因子修正后的化学质量平衡模型(EPA CMB8.2)对表层沉积物中PAHs的来源进行定量解析.结果表明研究区域内表层沉积物中PAHs的主要来源为燃煤源(工业燃煤、民用燃煤)、柴油燃烧和柴油泄漏,其相对贡献率分别为75.70%,15.05%和9.25%.

关 键 词:源解析  表层沉积物  多环芳烃  化学质量平衡  降解因子

Identification and Source Spportionment of Polycyclic Aromatic Hydrocarbons(PAHs) in Coastal Surface Sediments from Rizhao Offshore Area
LANG Yin-Hai,XUE Li-Dong,LIU Ai-Xia,LIU Jie.Identification and Source Spportionment of Polycyclic Aromatic Hydrocarbons(PAHs) in Coastal Surface Sediments from Rizhao Offshore Area[J].Periodical of Ocean University of China,2009,39(3).
Authors:LANG Yin-Hai  XUE Li-Dong  LIU Ai-Xia  LIU Jie
Institution:Key Lab of Marine Environmental Science and Ecology;Ministry of Education;College of Environmental Science and Engineering;Ocean University of China;Qingdao 266100;China
Abstract:Polycyclic Aromatic Hydrocarbons(PAHs) in coastal surface sediments from Rizhao offshore area were analyzed by GC-MS.The relative abundance between the low ring PAHs and the median and high ring PAHs as well as the isomeric ratios showed that the main source of PAHs were coal residential(CR),coal power plant(CP),diesel engines exhaust(DE),gasoline engines exhaust(GE),coke oven(CO),diesel oil leaks(DOL) and wood burning(WB).Source profiles were collected from literatures to establish the fingerprints of seve...
Keywords:source apportionment  surface sediments  PAHs  CMB model  degradation factor  
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