| 化学发光法测定天然水体中低浓度硝酸盐和亚硝酸盐的含量 |
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| 引用本文： | 王 燕,刘素美,任景玲,张桂玲.化学发光法测定天然水体中低浓度硝酸盐和亚硝酸盐的含量[J].海洋科学,2011,35(5):95-99. |
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| 作者姓名： | 王 燕 刘素美 任景玲 张桂玲 |
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| 作者单位： | 中国海洋大学海洋化学理论与工程技术教育部重点实验室,山东青岛,266100 |
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| 基金项目： | 国家自然科学基金项目(40876054, 40730847); 教育部科学技术研究重点项目(108081); 科技部国家重点基础研究发展计划项目(2006CB4006) |
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| 摘 要： | 传统分光光度法测定硝酸盐和亚硝酸盐含量时检测限较高,无法测定部分海洋表层及寡营养盐海域低含量的硝酸盐和亚硝酸盐浓度,急需采用一种新的测定低浓度硝酸盐和亚硝酸盐的方法.化学发光法用于测定水体中硝酸盐和亚硝酸盐含量,具有灵敏度高、检测限低、样品用量少,不受悬浮颗粒物、有色物质影响及样品批量测定等优点.本文通过探索载气流速、...
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| 关 键 词： | 硝酸盐 亚硝酸盐 化学发光法 低浓度 天然水体 |
| 收稿时间： | 2009/6/20 0:00:00 |
| 修稿时间： | 2009/9/30 0:00:00 |
Chemiluminescent measurement of low concentrations of nitrate and nitrite |
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| WANG Yan,LIU Su-mei,REN Jing-ling,ZHANG Gui-ling.Chemiluminescent measurement of low concentrations of nitrate and nitrite[J].Marine Sciences,2011,35(5):95-99. |
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| Authors: | WANG Yan LIU Su-mei REN Jing-ling ZHANG Gui-ling |
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| Abstract: | Chemiluminescent technique was applied for the determination of nanomolar quantities of nitrate and nitrite. Suspended particles and chromaphores did not interfere and were hence not necessary to be removed. The optimal experimental conditions with detection limit of 10 nmol/L were set up in the laboratory. The relative standard deviation was 5% at the 200 nmol/L level and 3% at the 400 nmol/L level. At wider detected range, greater accuracy and precision were obtained for this technique comparing to the conventional spectrophotometric methods. Consistent results were obtained when the concentrations of nitrate and nitrite in seawater and river water samples were measured using these two methods. |
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| Keywords: | nitrate nitrite low concentration natural water chemiluminescence |
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