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江西省鄱阳湖流域根系土硒形态分析及其迁移富集规律
引用本文:魏然,侯青叶,杨忠芳,尹国胜,衷存堤,邓国辉,马逸麟.江西省鄱阳湖流域根系土硒形态分析及其迁移富集规律[J].物探与化探,2012(1):109-113.
作者姓名:魏然  侯青叶  杨忠芳  尹国胜  衷存堤  邓国辉  马逸麟
作者单位:中国地质大学地球科学与资源学院;江西省地质调查院
基金项目:长江流域区域生态地球化学评价(GZTR20070201)
摘    要:对江西省鄱阳湖流域根系土中硒的形态分析表明,根系土中Se的强有机态、腐植酸结合态约占Se全量的66.23%,残渣态占12.32%,3种形态均与根系土Se全量呈极显著的线性正相关。根系土Se全量受pH值的影响不明显,但受有机质含量的影响很大,线性回归关系极显著,说明岩石风化、土壤发育过程中,有机质吸附Se,致使Se较其他元素流失比例少,造成根系土中Se相对富集。同时,提出了利用全量Se推导Se各形态值的方法,建立了土壤Se全量与各形态间的关系模型和决定土壤有效态Se的公式,建议在评价土壤Se时只用考虑有机结合态Se、残渣态Se、水溶态Se和全量Se。

关 键 词:  形态分析  迁移与富集  根系土

AN ANALYSIS OF SPECIATION OF SELENIUM AS WELL AS ITS TRANSFORMATION AND ENRICHMENT IN ROOT SOIL OF POYANG LAKE BASIN,JIANGXI PROVINCE
WEI Ran,HOU Qing-ye,YANG Zhong-fang,YIN Guo-sheng,ZHONG Cun-di,DENG Guo-hui,MA Yi-lin.AN ANALYSIS OF SPECIATION OF SELENIUM AS WELL AS ITS TRANSFORMATION AND ENRICHMENT IN ROOT SOIL OF POYANG LAKE BASIN,JIANGXI PROVINCE[J].Geophysical and Geochemical Exploration,2012(1):109-113.
Authors:WEI Ran  HOU Qing-ye  YANG Zhong-fang  YIN Guo-sheng  ZHONG Cun-di  DENG Guo-hui  MA Yi-lin
Institution:1.School of Earth Sciences and Resources,China University of Geosciences,Beijing 100083,China;2.Jiangxi Institute of Geological Survey,Nanch-ang 330030,China)
Abstract:Selenium speciation in root soil samples collected from the Poyang Lake basin of Jiangxi Province was investigated in this paper.The results show a significant positive correlation between the species and total amounts of selenium in root soil.The residue species of selenium occupies 12.32% of total selenium,and the species of bound-state humic acid approximately accounts for 66.23% of the total amount of selenium in root soil.Meanwhile,selenium abundance in root soil insignificantly varies with the change of pH value but is significantly influenced by organic content.It is held that the process of selenium adsorption in soil organic substance and clay mineral causes selenium enrichment in root soil.This paper has proposed a method for estimating speciation concentration of selenium according to the total selenium and established a formula to calculate available selenium content with given data of selenium abundance and speciation in soils.In addition,a suggestion is put forward that only selenium species of organic bound,residue,water soluble and total amount of selenium should be considered in soil selenium assessment.
Keywords:selenium  speciation analysis  transformation and enrichment  root soil
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