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Distribution of phthalate esters in the groundwater of Jianghan plain, Hubei, China
Authors:Dan Zhang  Hui Liu  Ying Liang  Cheng Wang  Hecheng Liang and Hesheng Cai
Institution:(1) Key Laboratory of Biogeology and Environmental Geology of Ministry of Education, School of Environmental Studies, China University of Geosciences, Wuhan, 430074, China
Abstract:Samples of groundwater were collected from 17 sites in the Jianghan plain in July 2007. Sixteen phthalate esters (PAEs) were detected in samples collected by using solid-phase extraction (SPE)-gas chromatography (GC). The results show that there were one or several PAEs in all the samples, and the concentrations of total PAEs ranged from 80.12 to 1882.18 ng/L. Four PAEs, i.e. di-isobutyl phthalate (DIBP), di-n-butyl phthalate (DBP), bis (2-ethoxyethyl) phthalate (BEEP) and di (2-ethylhexyl) phthalate DEHP) were the dominant species. Among these, DIBP, DBP and DEHP concentrations were closely related to the water supply from the Yangtze River, Hanjiang River and Honghu Lake. However, the distribution of BEEP was irregular, which may be due to the application of some kind of products containing BEEP in the related areas. PAE distribution was irrelevant to the electrical conductivity and sample depth.
Keywords:phthalate esters (PAEs)  groundwater  solid-phase extraction (SPE)  gas chromatography (GC)
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