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An Ion and Electron Microprobe Study of the Mineralogy of Enclaves and Host Syenites of the Red Hill Complex, New Hampshire, USA
Authors:DORAIS  MICHAEL J; FLOSS  CHRISTINE
Institution:1Department of Geological Sciences, Indiana University Bloomington, Indiana 47405
2Earth and Planetary Sciences Department, McDonnell Center for the Space Sciences, Washington University St. Louis, Missouri 63130
Abstract:The Red Hill complex of New Hampshire is unusual for the WhiteMountain Magma Series of northern New England because it consistsof both silica-undersaturated and -saturated to -oversaturatedsyenites. Amphibole, pyroxene, and apatite in two of the saturatedunits, the Outer Coarse Syenite (OCS) and the Garland Peak Syenite(GPS), and in the undersaturated Nepheline Sodalite Syenite(NSS), were analyzed to determine the relationship between coexistingunder-saturated and saturated magmas. Mafic enclaves in theNSS and the GPS were also studied to elucidate their relationshipswith the host syenites. In addition to mafic enclaves, the NSS contains later emplacedcamptonitic dikes and associated pipe-like benmoreites. Thebenmoreites contain amphibole that is compositionally continuouswith amphibole in the NSS. However, REE and other trace elementabundances in apatite from the benmoreites and the NSS are notcompatible with a genetic relationship between the two. Maficenclaves within the NSS contain amphibole and pyroxene thatare compositionally continuous with the NSS. Bulk-rock compositionsof the enclaves plot along trends defined by the NSS. Furthermore,chondrite-normalized REE patterns for apatite in both the enclavesand the NSS are parallel, and REE abundances increase systematicallyfrom the enclaves to the NSS. We therefore suggest that theenclaves represent magmas similar to the NSS parent that intrudedup into its daughter products. These magmas appear to have beentephritic to phonotephritic in composition. Abundances of REE in apatite in the Nepheline Sodalite Syenite(NSS) are distinct from those in apatite in the silica-saturatedOCS. OCS apatites have LREE abundances up to 26 000 times chondritesand La/Yb ratios of 16–27. NSS apatites have comparableLREE concentrations, but HREE abundances are considerably lowerthan those of the OCS; La/Yb ratios range from 68 to 104. Theseobserved differences in both the REE and other trace elementabundances between apatite in the two rocks present difficultieswith a common parental magma hypothesis for the NSS and OCS.Hence it is suggested that, although the OCS and NSS are contemporaneousin time and space, they are probably not consanguineous. The silica-saturated GPS is a fine-grained syenite containingstrongly zoned amphiboles with kaersutite to hastingsite coresrimmed by hastingsitic hornblende and ferro-hornblende. Discretegrains of hastingsitic hornblende and ferro-hornblende occurin a feldspar-quartz groundmass. Coarser-grained, quartz-richpatches, containing feldspars and ferro-hornblende and ferroedenite,are also found in the GPS. The kaersutite cores are identicalto the amphibole in the GPS enclaves and the NSS suite. TheseGPS enclaves are silica undersaturated; the kaersutite coresin the GPS host rocks are probably xenocrysts derived from disaggregatedundersaturated magmas similar to that represented by the enclaves.
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