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Enrichment of redox-sensitive trace metals (U,V, Mo,As) associated with the late Hauterivian Faraoni oceanic anoxic event
Authors:Stéphane Bodin  Alexis Godet  Virginie Matera  Philipp Steinmann  Jean Vermeulen  Silvia Gardin  Thierry Adatte  Rodolfo Coccioni  Karl B Föllmi
Institution:(1) Institut de Géologie, Université de Neuchatel, Rue Emile Argand 11, CP 158, 2009 Neuchatel, Switzerland;(2) Grand Rue, 04330 Barrême, France;(3) CNRS-UMR 5143 “Paléodiversité et Paléolenvironnement”, case 104, Université Paris 6, 4 Place Jussieu, 75252 Paris Cedex 05, France;(4) Istituto di Geologia e Centro di Geobiologia dell’Università, Campus Scientifico, Località Crocicchia, 61029 Urbino, Italy
Abstract:The Faraoni Level is a short-lived oxygen-deficient event that took place during the latest Hauterivian. In order to improve our understanding of the palaeoenvironmental conditions that occurred during this event, we have analysed the contents of several redox-sensitive trace elements (U, V, Mo, As, Co, Cd, Cu, Zn, Ni, Pb, Cr) from bulk limestone samples of late Hauterivian–early Barremian age from three reference sections. U, V, Mo and As show consistent and significant enrichments during the Faraoni event whereas the other redox-sensitive trace elements analysed here are not systematically enriched. In order to explain this discrepant behaviour, we propose that the Faraoni Level was deposited during a period of anoxic conditions near the sediment–water interface. The distinctive peaks in U, V, Mo and As contents are traceable throughout the three studied sections and represent a good correlation tool which helps to identify the Faraoni Level and its equivalents in the western Tethyan realm and outside of the Tethys. For example, a peak in U contents in upper Hauterivian sediments of the northwestern Pacific realm (ODP leg 185, site 1149) may well be an expression of the Faraoni event in this particular basin.
Keywords:Hauterivian  Barremian  Chemostratigraphy  Western Tethys  Trace metals
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