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湖南洞庭湖地区土壤酸化特征及机理研究
引用本文:杨忠芳,余涛,唐金荣,朱翠娟,宗思锋,张娇,张建新,申志军.湖南洞庭湖地区土壤酸化特征及机理研究[J].地学前缘,2006,13(1):105-112.
作者姓名:杨忠芳  余涛  唐金荣  朱翠娟  宗思锋  张娇  张建新  申志军
作者单位:1. 中国地质大学(北京)地球科学与资源学院,北京,100083
2. 中国地质调查局,发展研究中心,北京,100037
3. 湖南省地质研究所,湖南,长沙,410007
基金项目:中国地质调查局地质调查项目;中国农业生态地球化学评价体系研究与成果集成项目;湖南省洞庭湖农业生态地球化学评价项目
摘    要:湖南省洞庭湖地区是中国酸雨沉降和土壤酸化严重的地区之一,酸雨沉降具有明显的季节性和地域性差异,酸雨沉降与土壤酸化具有较好的空间对应性,但土壤酸化的程度还取决于土壤中盐基离子的含量。在土壤酸化较严重的地区,垂向上,土壤酸化深度已达50cm左右,土壤酸化伴随着大量的可溶性铝的溶出。在土壤pH值与盐基离子、氮和硫含量的关系曲线上,存在着pH值突变的临界点(临界点pH值为8),在碱性范围内,硅酸盐和铝硅酸盐矿物的水解使大量盐基离子溶出,中和了因SO42-和NO3-的输入而造成的土壤酸化,但当pH值下降到小于7·25的中酸性范围时,酸性物质和碱性物质组成的土壤缓冲体系失去缓冲作用,酸性物质略有增加,就会导致土壤迅速酸化。

关 键 词:土壤酸化  盐基离子  缓冲作用
文章编号:1005-2321(2006)01-0105-08
收稿时间:2005-10-21
修稿时间:2005-11-22

A study of the characteristics and mechanisms of soil acidification in the Dongting Lake region in Hunan Province, South China
YANG Zhong-fang,YU Tao,TANG Jin-rong,ZHU Cui-juan,ZONG Si-feng,ZHANG Jiao,ZHANG Jian-xin,SHEN Zhi-jun.A study of the characteristics and mechanisms of soil acidification in the Dongting Lake region in Hunan Province, South China[J].Earth Science Frontiers,2006,13(1):105-112.
Authors:YANG Zhong-fang  YU Tao  TANG Jin-rong  ZHU Cui-juan  ZONG Si-feng  ZHANG Jiao  ZHANG Jian-xin  SHEN Zhi-jun
Institution:1. School of Earth Science and Resources, China University of Geosciences, Beijing 100083, China ;2. The Centre of Development and Research, Geological Survey of China, Beijing 100037, China; 3. Geological Institute of Hunan , Changsha 410007, China
Abstract:Acid deposition and soil acidification occur more severely in the Dongting Lake region in Hunan Province, South China. Acid deposition appears to be seasonal. Regional differences show a close spatial correlation with soil acidification, whereas the extent of soil acidification depends on the content of electropositive ions. In severely acidified areas, soil acidification may occur at a depth of about 50 cm, and much AI dissolves out along with the soil acidification. There is a critical point on the curve of soil pH vs. the content of basic cations, S and N, which is corresponding to a pH of 8. In alkaline conditions, a large quantity of basic cations is dissolved owing to the hydrolysis of silicates and aluminosilicates. Hence the soil acidity that is due to the input of SO4^2- and NO3^- is neutralized. However, when the pH is below 7.25, the buffer system set up by acid and alkaline materials in soil is no longer effective. A little increase of acid material will rapidly trigger the soil acidification.
Keywords:soil acidification  basic catiom buffering
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