| 祁连造山带玉石沟地幔橄榄岩中挥发分的流体化学和稳定同位素组成及古大洋岩石圈演化意义 |
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| 引用本文： | 胡沛青 张铭杰 汤中立 LI Chusi 王记周.祁连造山带玉石沟地幔橄榄岩中挥发分的流体化学和稳定同位素组成及古大洋岩石圈演化意义[J].岩石学报,2007,23(1):169-176. |
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| 作者姓名： | 胡沛青 张铭杰 汤中立 LI Chusi 王记周 |
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| 作者单位： | Key Lab of Environmental System of Western China(MOE) Lanzhou University，Lanzhou 730000，China，Key Lab of Environmental System of Western China(MOE)，Lanzhou University，Lanzhou 730000，China，Key Lab of Environmental System of Western China(MOE)，Lanzhou University，Lanzhou 730000，China，Key Lab of Environmental System of Western China(MOE)，Lanzhou University，Lanzhou 730000，China |
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| 摘 要： | Fluid inclusions in olivine and orthopyroxene of mantle peridotites from the Yushigou ophiolite can be divided into three types based on decrepitation temperature,shape and distribution.Type-1 fluid inclusions are characterized by oval or negative crystal shapes and small size(<5μm across).They occur in the cores and mantles of the host crystals,and decrepitated at>840℃.Type- 2 fluid inclusions have irregular or tabular shapes with relatively large size(10～100μm in length).They occur in irregular or circular healed micro-fractures in the host crystals,and decrepitated at 612～710℃.Type-3 fluid inclusions have size and shape,similar to type-2 fluid inclusions but occur in micro-fractures restricted to the margins of the host crystals,and decrepitated at much lower temperature from 190℃to 340℃.The three different types of fluid inclusions are interpreted to represent primary,metasomatic (pseudo-secondary)and secondary inclusions,respectively.Stepwise heating reveals three concentration peaks of volatiles at 200～400℃,400～800℃and 800～1200℃released from olivine and orthopyroxene in harzburgite and dunite from the Yushigou ophiolite, which are considered to correspond to the decrepitation of secondary,metasomatic and primary fluid inclusions at similar temperature ranges.CO2 is a major constituent in the volatiles released at three different temperature intervals.Trace amounts of H_2 and N_2 are present in the volatiles released at<800℃and trace amounts of H_2O and SO_2 are mainly present in the volatiles at 400～800℃.TheδD(-95.2‰,-306.3‰)of H_2O and theδ~(13)C(-15.5～-12.5‰)andδ~(18)O values(1.4～1.9‰)of CO_2 released at<800℃are lower than normal mantle values and suggest the mixing origin of crustal fluids( sedimentary organic)with ocean water,implying that Yushigou AOLM had undergone an intensive metasomatism by a fluid composed of CO_2.H_2O and SO_2,and followed by degassing. In contrast,the volatiles released at 800～1200℃are characterized by trace amounts of H_2 and CO in dunite and SO_2 in harzburgite, much lighterδ~(13)C(-29.1‰～-19.5‰),heavierδ~(13)O(8.8‰)of CO_2 and positive relationship between these isotopic ratios and the concentration of CO_2.Such features can be best explained by mixing of significant terrestrial crustal(organic)and minor mantle volatiles.We proposed that the Yishigou peridotites are more likely to have derived from a continental lithosphere instead of an oceanic lithosphere comprising the Yishigou gabbros and pillowed basalts.A supra-subduction tectonic setting is thus inferred for the Yushigou ophiolite.
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| 关 键 词： | 祁连造山带 玉石沟地幔 橄榄岩 挥发分 流体化学 稳定同位素组成 古大洋 岩石圈 演化意义 |
| 文章编号： | 1000-0569/2007/023（01）-0169-76 |
| 修稿时间： | 2006-07-15 |
Chemical and stable isotopic compositions of volatiles in mantle peridotites of the Yushigou ophiolite in Qilian orogenic belt, western China |
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| HU PeiQing,ZHANG MingJie,TANG ZhongLi,LI ChuSi,WANG JiZhou,Lanzhou University,Lanzhou,China;.Chemical and stable isotopic compositions of volatiles in mantle peridotites of the Yushigou ophiolite in Qilian orogenic belt, western China[J].Acta Petrologica Sinica,2007,23(1):169-176. |
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| Authors: | HU PeiQing ZHANG MingJie TANG ZhongLi LI ChuSi WANG JiZhou Lanzhou University Lanzhou China; |
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| Institution: | 1. Key Lab of Environmental System of Western China (MOE), Lanzhou University, Lanzhou 730000, China
2. Department of Geological Sciences, Indiana University, IN 47405, USA |
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| Abstract: | Fluid inclusions in olivine and orthopyroxene of mantle peridotites from the Yushigou ophiolite can be divided into three types based on decrepitation temperature, shape and distribution. Type-1 fluid inclusions are characterized by oval or negative crystal shapes and small size ( ＜ 5μm across). They occur in the cores and mantles of the host crystals, and decrepitated at ＞ 840℃. Type2 fluid inclusions have irregular or tabular shapes with relatively large size ( 10 ～ 100μm in length). They occur in irregular or circular healed micro-fractures in the host crystals, and decrepitated at 612 ～710℃. Type-3 fluid inclusions have size and shape similar to type-2 fluid inclusions but occur in micro-fractures restricted to the margins of the host crystals, and decrepitated at much lower temperature from 190℃ to 340℃. The three different types of fluid inclusions are interpreted to represent primary, metasomatic (pseudo-secondary) and secondary inclusions, respectively. Stepwise heating reveals three concentration peaks of volatiles at 200 ～400℃, 400 ～ 800℃ and 800 ～ 1200℃ released from olivine and orthopyroxene in harzburgite and dunite from the Yushigou ophiolite, which are considered to correspond to the decrepitation of secondary, metasomatic and primary fluid inclusions at similar temperature ranges. CO2 is a major constituent in the volatiles released at three different temperature intervals. Trace amounts of H2 and N2 are present in the volatiles released at ＜ 800℃ and trace amounts of H2O and SO2 are mainly present in the volatiles at 400 ～ 800℃. The δD ( -95.2‰, -306.3‰) of H2O and the δ13C ( -15.5 ～ -12.5‰) and δ18O values (1.4 ～ 1.9‰) of CO2 released at ＜800℃ are lower than normal mantle values and suggest the mixing origin of crustal fluids ( sedimentary organic) with ocean water, implying that Yushigou AOLM had undergone an intensive metasomatism by a fluid composed of CO2, H2O and SO2, and followed by degassing. In contrast, the volatiles released at 800 ～ 1200℃ are characterized by trace amounts of H2 and CO in dunite and SO2 in harzburgite, much lighter δ13C ( -29.1‰～ - 19.5‰), heavier δ13O (8.8‰) of CO2 and positive relationship between these isotopic ratios and the concentration of CO2. Such features can be best explained by mixing of significant terrestrial crustal (organic) and minor mantle volatiles. We proposed that the Yishigou peridotites are more likely to have derived from a continental lithosphere instead of an oceanic lithosphere comprising the Yishigou gabbros and pillowed basalts. A supra-subduction tectonic setting is thus inferred for the Yushigou ophiolite. |
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| Keywords: | Fluid inclusions Volatiles Stable isotopes Peridotites Ophiolite Qilian orogenic belt |
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