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江西永平铜矿矽卡岩矿物特征及其地质意义
引用本文:田明君,李永刚,万浩章,张宇,高婷婷.江西永平铜矿矽卡岩矿物特征及其地质意义[J].岩石学报,2014,30(12):3741-3758.
作者姓名:田明君  李永刚  万浩章  张宇  高婷婷
作者单位:中国科学院地质与地球物理研究所, 北京 100029;中国科学院大学, 北京 100049;中国科学院地质与地球物理研究所, 北京 100029;江西地矿局九一二大队, 鹰潭 35000;中国科学院地质与地球物理研究所, 北京 100029;中国科学院大学, 北京 100049;中国科学院地质与地球物理研究所, 北京 100029;中国科学院大学, 北京 100049
基金项目:本文受大中型企业委托项目(Y118305183)资助.
摘    要:永平铜矿含矿岩石主要为绿帘石透辉石石榴石矽卡岩,这种岩石类型是与斑岩体有关的矽卡岩铜矿的典型赋矿岩石。通过对这一主要赋矿矽卡岩的研究,我们发现石榴石生长分为两个阶段:(1)早期石榴石:主要分布在石榴石颗粒核部,XAdr=1.0,主要以钙铁榴石为主,说明早期流体中可能含有较多的铁,是在较氧化条件下形成的;(2)晚期石榴石,沿石榴石裂隙重新成核或者在靠近流体通道的早期石榴石表面生长,出现震荡环带,XAdr=0.46~0.99,为钙铁-钙铝石榴石系列。石榴石发生变化的期间也形成新的矿物,如绿帘石、萤石、方解石和石英等。共存石榴石和绿帘石矿物中存在Fe3+-Al3+之间的替代,说明流体的氧逸度、组分浓度或aFe3+/aAl3+可能发生了变化。金属矿物也可能是在这一阶段形成的。永平铜矿矽卡岩从接触带到大理岩空间上有分带现象。从岩体到围岩的变化趋势为:石榴石含量减少,颜色存在红棕色-棕色-棕绿色-黄绿色-浅黄色的变化趋势;矿石品位降低,这与石榴石中Al2O3含量的变化较一致。我们认为这种变化是含矿热液对早期矽卡岩进行再交代改造的结果,表现为石榴石和绿帘石中Fe3+-Al3+含量的变化,并将Cu等金属沉淀下来。根据矽卡岩矿物的这些特征,在矿床勘探时,可依据棕色石榴石来追踪主矿体的位置。

关 键 词:永平铜矿  石榴石  绿帘透辉石榴石矽卡岩  矿床分带  江西
收稿时间:2014/2/13 0:00:00
修稿时间:2014/10/17 0:00:00

Characteristics of skarn minerals in Yongping copper deposit, Jiangxi Province, and geological significances
TIAN MingJun,LI YongGang,WAN HaoZhang,ZHANG Yu and GAO TingTing.Characteristics of skarn minerals in Yongping copper deposit, Jiangxi Province, and geological significances[J].Acta Petrologica Sinica,2014,30(12):3741-3758.
Authors:TIAN MingJun  LI YongGang  WAN HaoZhang  ZHANG Yu and GAO TingTing
Institution:Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;University of Chinese Academy of Sciences, Beijing 100049, China;Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;912 Geological Party of JBEDGMR, Yintan 35000, China;Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;University of Chinese Academy of Sciences, Beijing 100049, China;Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;University of Chinese Academy of Sciences, Beijing 100049, China
Abstract:The main ore skarn in Yongping copper deposit is epidote diopside garnet skarn, which is typical ore-bearing skarn related to porphyry intrusion. On the basis of study on the main ore-bearing garnet skarns, we divided the garnets into two generations: (1) an early generation of garnets, distributing at the core of garnet crystal, XAdr=1.0, and mainly of andradite, indicating an oxidized state; (2) a late generation of garnets, which is generally nucleated along garnet cracks, or on the surface of the early garnets near the fluid channels, with oscillatory zonation, and belongs to andradite-grossularite series with XAdr=0.46~0.99. Other minerals formed during garnet replacement process include epidote, fluorite, calcite, quartz and so on. Partitioning of Fe3+-Al3+ among coexisting garnet and epidote solid solutions may reflect variations of oxygen fugacity, component concentration and/or aFe3+/aAl3+. Metal minerals would also precipitate from this period. Skarn in the Yongping deposits has a general spatial zonation-within the contact zone between skarn and marble. From the pluton to wall rock, the content of garnet decreases, and its color changes from red-brown, brown, brown-green, yellow-green, to light-yellow. Moreover, the ore grade decreases coincidently with the Al2O3 content of garnet. We consider that these changes are result of metasomatism between ore-bearing hydrothermal fluid and early skarns, represented by Fe3+-Al3+ substitution in garnet and epidote. This trend of skarn minerals in ore deposits may be used as a guide for deposits exploration.
Keywords:Yongping copper deposit  Garnet  Epidote diopside garnet skarn  Mineral zonation  Jiangxi Province
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