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硫酸钡的氧硫同位素分析方法及有关数据的地质应用实例
引用本文:赵瑞,沈延安.硫酸钡的氧硫同位素分析方法及有关数据的地质应用实例[J].岩石学报,1995,11(3):320-324.
作者姓名:赵瑞  沈延安
作者单位:中国科学院地质研究所
摘    要:碳粉在高温条件下可还原硫酸钡,使其氧转入CO2及CO气体中。此CO气体在高温镍金属的催化作用下,可转化为CO2气体。两种CO2合并后,可用质谱计分析其氧同位素组成。此组成便是硫酸钡的δ(18)O值。水体硫酸根的氧、硫同位素值在水环境研究中大有用处。例如,三山岛金矿矿井水中硫酸根的氧、硫同位素数据表明,此水是地下水及海水的混合产物。这就为矿井排水工程的设计提供出某种信息。

关 键 词:硫酸钡,氧同位素分析,硫同位素分析,碳还原法

An Analytical Method of Oxygen and Sulfur Isotope Compositions of BaSO_4 and Their Practical Appl ication to Geology Research
Zhao Rui,Shen Yanan,Xie Yihan,Huo Weiguo and Yao Yiguan.An Analytical Method of Oxygen and Sulfur Isotope Compositions of BaSO_4 and Their Practical Appl ication to Geology Research[J].Acta Petrologica Sinica,1995,11(3):320-324.
Authors:Zhao Rui  Shen Yanan  Xie Yihan  Huo Weiguo and Yao Yiguan
Abstract:Carbon powder can reduce BaSO4 at hypothermal temperature to produce CO,and CO.The CO can be changed to CO2 in catalytic process of hypothermal nickel metal. Oxygen isotope composition of the sum CO2 is the value of BaSO4. The oxygen and sulfur isotope compositions of SO-dissoved in water play an important role in the research of water environment. For example,the oxygen and sulfur isotope compositions of SO- dissolved in subsurface water of Sanshandao gold mine show that the mining water is a product of mixing of sea water and mine subsurface water.
Keywords:Barium sulfate  Oxygen isotope composition analysis  Sulfur isotope composition analysis  Carbon reduction method
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