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电感耦合等离子体发射光谱法测天然饱和卤水中的高含量锂
引用本文:袁红战,祝云军,武丽平,张旭.电感耦合等离子体发射光谱法测天然饱和卤水中的高含量锂[J].岩矿测试,2011,30(1):87-89.
作者姓名:袁红战  祝云军  武丽平  张旭
作者单位:青海省柴达木综合地质矿产勘查院西部岩矿测试中心,青海,格尔木816000
摘    要:建立了电感耦合等离子体发射光谱测定天然饱和卤水中锂的方法,研究了基体元素对锂元素的干扰,采用基体匹配法克服了基体效应的影响.方法加标回收率为97.4%~101.5%,检出限为1.02 mg/L,精密度(RSD,n=12)为1.21%.方法快速准确,可以准确测定天然饱和卤水中的锂.

关 键 词:  天然饱和卤水  电感耦合等离子体发射光谱法  基体干扰
收稿时间:2010/4/19 0:00:00
修稿时间:2010/8/30 0:00:00

Determination of High-content of Lithium in Natural Saturated Brines by Inductively Coupled Plasma-Atomic Emission Spectrometry
YUAN Hong-zhan,ZHU Yun-jun,WU Li-ping and ZHANG Xu.Determination of High-content of Lithium in Natural Saturated Brines by Inductively Coupled Plasma-Atomic Emission Spectrometry[J].Rock and Mineral Analysis,2011,30(1):87-89.
Authors:YUAN Hong-zhan  ZHU Yun-jun  WU Li-ping and ZHANG Xu
Institution:Testing Center of Qinghai Chaidamu Comprehensive Geological and Mineral Exploration Academy, Geermu 816000, China;Testing Center of Qinghai Chaidamu Comprehensive Geological and Mineral Exploration Academy, Geermu 816000, China;Testing Center of Qinghai Chaidamu Comprehensive Geological and Mineral Exploration Academy, Geermu 816000, China;Testing Center of Qinghai Chaidamu Comprehensive Geological and Mineral Exploration Academy, Geermu 816000, China
Abstract:A method for the determination of high-content of lithium in natural saturated brines by inductively coupled plasma-atomic emission spectrometry (ICP-AES) was developed. The sample was directly determined by ICP-AES with sample dilution factor of 10. The interference from matrix elements on Li determination was studied and matrix marching method was used for matrix effect correction. The detection limit of the method for Li was 1.02 mg/L and recoveries was the ranged of 97.4% to 101.5% with the precision of 1.21% RSD (n=12). The method has been applied to the determination of Li in natural saturated brine with advantages of good accuracy and high efficiency.
Keywords:lithium  natural saturated brine  inductively coupled plasma-atomic emission spectrometry  matrix interference
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