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基于电感耦合等离子体质谱/光谱技术研究朱溪钨铜矿床原生晕地球化学特征
引用本文:苏晓云,刘善宝,高虎,王成辉,刘战庆,胡正华,刘建光,陈国华,万浩章.基于电感耦合等离子体质谱/光谱技术研究朱溪钨铜矿床原生晕地球化学特征[J].岩矿测试,2015,34(2):252-260.
作者姓名:苏晓云  刘善宝  高虎  王成辉  刘战庆  胡正华  刘建光  陈国华  万浩章
作者单位:中煤科工集团西安研究院有限公司, 陕西 西安 710077;,中国地质科学院矿产资源研究所, 北京 100037;,陕西省核工业地质调查院, 陕西 西安 710054;,中国地质科学院矿产资源研究所, 北京 100037;,桂林理工大学地球科学学院, 广西 桂林 541004;,江西省地质调查研究院, 江西 南昌 330201;,江西省地质矿产勘查开发局九一二大队, 江西 鹰潭 335001,江西省地质矿产勘查开发局九一二大队, 江西 鹰潭 335001,江西省地质矿产勘查开发局九一二大队, 江西 鹰潭 335001
基金项目:江西省地质勘查基金项目“江西省塔前—赋春铜多金属成矿带成矿规律与成矿预测”(20120106);中煤科工集团西安研究院有限公司科技创新青年基金项目“煤层典型构造的槽波响应特性研究”(2015XAYQN07)
摘    要:江西朱溪钨铜矿是近年新发现的具有超大型规模前景的钨铜矿床,本文采集了大量朱溪钨铜矿床样品,用偏振激发能量色散X射线荧光光谱、电感耦合等离子体质谱/光谱等技术分析主量和微量元素含量,根据各元素的含量水平以10种主要成矿元素(W、Sn、Bi、Mo、Pb、Zn、Cu、As、Sb、Ag)作为分析研究区原生晕地球化学特征的指示元素。结果表明,Cu、Zn、Ag、Pb和W、Bi、Sn、Mo的元素共生组合十分明显,同时W与Cu也有相关性,富集W的部位同样也富集了Cu。成矿元素在空间上的分布特征为:1同一剖面上越往北西方向,W为主的高温元素更为富集;平面上越往南西方向,W为主的高温元素更为富集;越往深部,W为主的高温元素更为富集。2Cu为主的中温元素富集深度比W为主的高温元素富集深度浅。研究认为,铜矿富集部位在中、深部(-1400~-1500 m),钨矿富集部位在深部(-1400~-1900 m),Ag、As、Sb等低温元素的富集部位更靠近地表(-1100~-1200 m)。这种剖面线上和平面上的原生晕地球化学特征为该矿床进一步勘探工作与成矿预测提供了理论依据。

关 键 词:朱溪钨铜矿床  原生晕  地球化学特征  偏振激发能量色散X射线荧光光谱法  电感耦合等离子体质谱法  电感耦合等离子体光谱法
收稿时间:2014/8/20 0:00:00
修稿时间:3/5/2015 12:00:00 AM

Research on Geochemistry Characteristics of the Primary Halo of Zhuxi Tungsten-Copper Deposit Based on ICP-MS/AES Techniques
SU Xiao-yun,LIU Shan-bao,GAO Hu,WANG Cheng-hui,LIU Zhan-qing,HU Zheng-hu,LIU Jian-guang,CHEN Guo-hua and WAN Hao-zhang.Research on Geochemistry Characteristics of the Primary Halo of Zhuxi Tungsten-Copper Deposit Based on ICP-MS/AES Techniques[J].Rock and Mineral Analysis,2015,34(2):252-260.
Authors:SU Xiao-yun  LIU Shan-bao  GAO Hu  WANG Cheng-hui  LIU Zhan-qing  HU Zheng-hu  LIU Jian-guang  CHEN Guo-hua and WAN Hao-zhang
Institution:Xi'an Research Institute, China Coal Technology and Engineering Group Corporation, Xi'an 710077, China;,Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China;,Shaanxi Nuclear Industry Geology Surveying Institute, Xi'an 710054, China;,Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China;,College of Earth Sciences, Guilin University of Technology, Guilin 541004, China;,Geological Survey of Jiangxi Province, Nanchang 330201, China;,No.912 Team, Jiangxi Bureau of Geological Exploration and Exploitation of Mineral Resources, Yingtan 335001, China,No.912 Team, Jiangxi Bureau of Geological Exploration and Exploitation of Mineral Resources, Yingtan 335001, China and No.912 Team, Jiangxi Bureau of Geological Exploration and Exploitation of Mineral Resources, Yingtan 335001, China
Abstract:A new tungsten-copper deposit with large-super mineralization potential was recently discovered in the Zhuxi area, Jingdezhen city of Jiangxi Province. The primary halo research plays a very important guiding role in further exploration work. By using Polarized Energy Dispersive X-ray Fluorescence Spectrometry, Inductively Coupled Plasma-Mass Spectrometry/Atomic Emission Spectrometry, large amounts of sample analyses have been conducted. According to the contents of elements W, Sn, Bi, Mo, Pb, Zn, Cu, As, Sb and Ag, these are served as the indicators of the primary halo. The primary halo of Zhuxi tungsten-copper deposit shows that Cu, Zn, Ag and Pb have good correlation as well as W, Bi, Sn and Mo. W is also correlated with Cu. The ore-forming elements have some characteristics in space. In the same section, high temperature elements such as W are more enriched at the northwest, whereas in the plane, this performance appeared at the southwest. Overall, W-oriented high-temperature elements are more enriched at lower depths. By comparison, Cu-oriented middle-temperature elements are shallower than W. This study indicates that the Cu deposit is distributed in the medium deep part (-1400--1500 m), W deposit in the deep part (-1400--1900 m) and Ag, As, Sb at the surface (-1100--1200 m). This study provides a theoretical basis for mineralization forecast and further exploration.
Keywords:Zhuxi tungsten and copper deposit  primary halo  geochemistry characteristics  Polarized Energy Dispersive X-ray Fluorescence Spectrometry  Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)  Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES)
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