偶氮氯磷-mN直接光度法测定矿石中铈族稀土元素 |
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引用本文: | 叶年咏.偶氮氯磷-mN直接光度法测定矿石中铈族稀土元素[J].岩石矿物学杂志,1983,2(3):222-223. |
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作者姓名: | 叶年咏 |
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作者单位: | 广东省地质局第九实验室 |
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摘 要: | 本文研究了偶氮氯膦-mN在磷酸—草酸—焦磷酸钠体系中以锌-EDTA二乙酯作缓冲掩蔽剂①在钇族稀土和常见元素存在下,不经分离,直接测定铈族稀土元素的可能性。一、实验部分偶氮氯膦-mN:0.05%水溶液(上海师大)。Zn-EDTA二乙酯0.15%水溶液:称取EDTA二乙酯15克,乙酸锌15克溶于1000毫升水中,摇均。混合铈组稀土标准:用光谱纯的稀土氧化物按
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Direct Spectrophotometric Determination of Microamount of Cerium-Group Rare Earths in Minerals and Rocks with Chlorophosphonazo-mN |
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Abstract: | This paper presents a direct rapid spectrophotometric method to deter-
mine the cerium-group rare earth elements in minerals and rocks with
chlorophosphonazo-mN as a developing reagent. Oxalic acid, phosphoric acid
a} sodium pyrophosphate were used as masking agents for yttrium-group
earths and Zn-EDTA-diethylester as masking agent for other foreign ions. |
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