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尾矿中硫化物风化氧化模拟实验研究
引用本文:陈天虎,冯军会,徐晓春,陈兴海,崔龙鹏.尾矿中硫化物风化氧化模拟实验研究[J].岩石矿物学杂志,2002,21(3):298-302.
作者姓名:陈天虎  冯军会  徐晓春  陈兴海  崔龙鹏
作者单位:1. 合肥工业大学,资源与环境科学系,安徽,合肥,230009
2. 安徽理工大学,资源与环境工程系,安徽,淮南,232001
基金项目:国家自然科学基金资助项目 (40 0 72 0 17),安徽省自然科学基金资助项目 (0 0 0 4 5 313)
摘    要:为防治矿山尾矿造成环境污染,对方铅矿,闪锌矿,磁黄铁矿、黄铜矿,黄铁矿进行了风化氧化实验研究,结果显示,硫化物的氧化速率顺序为:方铅矿>闪锌矿>磁黄铁矿>黄铜矿>黄铁矿,侵蚀液pH值越低,硫化物氧化速率越大,有机物存在对硫化物氧化起缓冲和抑制作用。

关 键 词:尾矿  硫化物  风化  氧化  模拟实验  有机物  环境污染
文章编号:1000-6524(2002)03-0298-05
修稿时间:2001年5月7日

Simulation experiments on weathering and oxidation of sulfide minerals in mine tailings
CHEN Tian_hu,FENG Jun_hui,XU Xiao_chun,CHEN Xing_hai and CUI Long_peng.Simulation experiments on weathering and oxidation of sulfide minerals in mine tailings[J].Acta Petrologica Et Mineralogica,2002,21(3):298-302.
Authors:CHEN Tian_hu  FENG Jun_hui  XU Xiao_chun  CHEN Xing_hai and CUI Long_peng
Institution:CHEN Tian_hu 1,FENG Jun_hui 1,XU Xiao_chun 1,CHEN Xing_hai and CUI Long_peng 2
Abstract:The weathering and oxidation of sulfides within mine tailings lead to acid drainage and release of heavy metals, which pollute ground water and surface water and damage ecological environment. Recent researches show that many factors can affect weathering of mine tailings. This paper points out that grain sizes, pH values and concentrations of organic matters in mine tailings can affect weathering and oxidation of sulfides. The qualitative observation and quantitative test of sulfides with optic microscope indicate that the rate of oxidation follows the sequence of PbS>ZnS>Fe 1-x S>CuFeS 2>FeS 2 within sulfides of the same grain size. The experimental results also suggest that organic matters in mine tailings can prevent sulfide minerals from weathering and oxidation.
Keywords:mine tailing  sulfide minerals  weathering  oxidation  simulation experiment  
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