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基于15N同位素技术的岩溶地下河硝酸盐污染变化特征研究——以重庆青木关地下河为例
引用本文:王开然,贾亚男,胡大超.基于15N同位素技术的岩溶地下河硝酸盐污染变化特征研究——以重庆青木关地下河为例[J].中国岩溶,2013,32(1):57-63.
作者姓名:王开然  贾亚男  胡大超
作者单位:西南大学地理科学学院;中国地质科学院岩溶地质研究所/国土资源部、广西壮族自治区岩溶动力学重点实验室;西南大学地理科学学院;湖南有色地质勘查局
基金项目:国家自然科学基金项目(41101036、41102161)
摘    要:根据2010年5月至2010年10月每月对青木关地下河河水的监测数据,利用”N同位素技术并结合水化学指标,分析地下河的水化学特征以及硝态氮来源的时空变化特征。结果表明,地下河出口丁家龙洞硝态氯浓度(5.077mg/I。)比入口天池硝态氮浓度(0.842mg/L)高6倍多。入口天池处地下河河水硝态氮浓度比较低,15N浓度变化范围为-7.0475‰~+7.059‰,变化幅度不大,说明该点的氮污染较低,地下水受外界影响较小,污水和粪便不是主要的δ15N来源。出口丁家龙洞处的δ15N浓度变化范围在-21.453‰~+37.825‰,总体浓度高且变化幅度大,受上游养猪场粪便直接排入及降水影响较大。

关 键 词:地下河  15N同位素  硝态氮  变化特征
收稿时间:2011/12/21 0:00:00

Variation features of nitrate pollution in karst underground river based on is N isotope techniques: A case study in the Qingmuguan underground river, Chongqing
WANG Kai ran,JIA Ya nan and HU Da chao.Variation features of nitrate pollution in karst underground river based on is N isotope techniques: A case study in the Qingmuguan underground river, Chongqing[J].Carsologica Sinica,2013,32(1):57-63.
Authors:WANG Kai ran  JIA Ya nan and HU Da chao
Institution:1.College of Geographical Sciences,Southwest University,Chongqing 400715,China; 2.Institute of Karst Geology,CAGS / Karst Dynamics Laboratory,MLR & GZAR,Guilin,Guangxi 541004,China; 3.Hunan Bureau of Non-ferrous Geological Exploring,Chenzhou,Hunan 423400,China)
Abstract:Groundwater in the Qingmuguan underground river is monitored with hydrochemistry and ~N iso- tope techniques to investigate temporal and spatial variations of nitrate-nitrogen and its possible sources from May, 2010 to October, 2010. The results show that nitrate concentrations are 5. 077 mg/L at the Dingjia- longdong outlet and 0. 842 mg/L at the Tianchi inlet of the underground river. Nitrate concentrations of the groundwater are low at the Tianchi inlet, and the change range of the a~SN concentration is low, from --7. 0475 %0 to +7. 059 %0, which proves that the Tianchi inlet only polluted by nitrogen slightly and the outside influence to groundwater also slight, and the sewage and feces are not the major source of alSN in this point. The concentration of alSN at the Dingjialongdong outlet ranges, overall high and changes much more exten- sively, from --21. 453 X0 to +37. 825 %0. That proves the Dingjialongdong is affected more strongly by di- rect emission of feces from the pig farm and precipitation.
Keywords:underground river  15N isotope  nitrate nitrogen  change characteristics
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