Compositional variability of spinel-group minerals from the shergol serpentinized peridotites along indus suture zone,ladakh himalaya (India): constraints on tectonomagmatic history |
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| Institution: | 1. Department of Geological Sciences and Engineering, Missouri University of Science and Technology, Rolla, MO, USA;2. Department of Geosciences, University of Arizona, Tucson, AZ, USA;3. University of Bucharest, Department of Geology and Geophysics, Bucharest, Romania;4. Deptartment of Earth and Atmospheric Science, City College of New York, New York, NY, USA;1. State Key Laboratory of Mineral Deposit Research, School of Earth Sciences and Engineering, Nanjing University, Nanjing 210093, China;2. Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;3. Department of Earth and Environmental Sciences, University of Milano-Bicocca, 20126 Milano, Italy;4. Department of Mining Engineering, Lvliang University, Lvliang 033000, Shanxi, China |
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| Abstract: | The Shergol ophiolitic peridotites along ISZ, Ladakh Himalaya are serpentinized to various degrees and are harzburgite in composition. Electron microprobe analyses of spinels from Shergol Serpentinized Peridotites (SSPs) were carried out in order to evaluate their compositional variation with alteration. Chemical discontinuity was observed from core to rim in analyzed spinel grains with Cr-rich cores rimmed by Cr-poor compositions. From unaltered cores to rims it was observed that Cr3+# and Fe3+# increases while Mg2+# decreases due to Mg2+ − Fe2+ and Al3+ (Cr3+) − Fe3+ exchange with surrounding silicates during alteration. These peridotites contain Al-rich spinels forming subhedral to anhedral grains with lobate and corroded grain boundaries; altered to ferritchromite or magnetite along cracks and boundaries by later metamorphism episode. The unaltered Cr-spinel cores are identified as Al-rich and are characterized by lower values of Cr3+# (0.34–0.40), high Al3+# (0.58–0.68) and Mg2+# (0.52–0.70). Mineral chemistry of these Al-rich Cr-spinels suggest that host peridotites have an affinity to abyssal and alpine-type peridotites. High TiO2 concentration of magmatic Cr-spinel cores are in agreement with MORB melt-residual peridotite interaction. Presence of unaltered magmatic Cr-spinel cores suggest that they do not have re-equilibrated completely with metamorphic spinel rims and surrounding silicates. Cr-spinel core compositions of SSPs suggest an ophiolitic origin derivation by low degrees of melting of a less-moderate depleted peridotite in a mid-ocean ridge tectonic setting. Based on textural and chemical observations the alteration conditions of studied spinel-group minerals match those of transitional greenschist-amphibolite facies metamorphism consistent with estimated metamorphic equilibration temperature of ∼ 500–600 °C. |
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| Keywords: | Ladakh himalaya Shergol peridotites Cr-spinel chemistry Melt-rock interaction |
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