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核磁共振(NMR)波谱技术对熔体结构研究的贡献
引用本文:朱永峰,赵永超,古丽冰.核磁共振(NMR)波谱技术对熔体结构研究的贡献[J].地质科技情报,1994(4).
作者姓名:朱永峰  赵永超  古丽冰
作者单位:北京大学地质学系
摘    要:核磁共振(NMR)波谱技术的应用极大地促进了对熔体结构的研究,获得了巨大的成就,主要表现在以下几个方面:成网离子在熔体结构中的分布特征;桥氧和非桥氧的有序-无序特征以及非桥氧环境的变化与熔体结构的关系;变网离子在熔体中的结构意义及地位;键角与键长的分布特征;温度对非桥氧环境的制约关系等。NMR技术的发展使对熔体结构有序化机制的研究终于成为可能。

关 键 词:核磁共振(NMR),熔体结构,贡献

NMR TECHNOLOGY AND ITS CONTRIBUTION TO THE STUDY OF MELT STRUCTURES
Zhu Yongfeng, Zhao Yongchao,Gu Libing.NMR TECHNOLOGY AND ITS CONTRIBUTION TO THE STUDY OF MELT STRUCTURES[J].Geological Science and Technology Information,1994(4).
Authors:Zhu Yongfeng  Zhao Yongchao  Gu Libing
Abstract:The development of NMR technology has enabled us to get a new picture of many petrological problems,including the relationship between the physical properties of magma (i.e.density,viscosity,and relaxation of melt structure) and the volatiles (their types and/ or contents),and the reacting mechanism of water with silicate melts.This paper reviews the progress in the research of melt structures in the following aspects:the order-disorder characteristics of the distribution of bridge and nonbridge oxygens in melt structures;the distribution of the bridge length and bridge angle in melt structures;and the distribution characteristics of the network-forming elements;the dynamical property of melt structures.
Keywords:nuclear  magnetic resonance(NMR)  melt (glass) struture  contribution  
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