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Open burning of wastes as the source of environmental contamination by POPs
作者姓名:Sergey  V.  Kakareka  Tamar  I.  Kukharchyk
作者单位:Institute for Problems of Natural Resources Use & Ecology, Minsk, Belarus
摘    要:In the paper the procedure for and results of a test study of a few persistent organic pollutants - polycyclic aromatic hydrocarbon (PAH), polychlorinated biphenyls (PCB) and hexachlorobenzene (HCB) emission from the open burning of different types of wastes (domestic wastes, agricultural debris, landscape cleating debris, etc.) are discussed. The open burning of agricultural debris and landscape-clearing debris is widely applied in rural areas and small towns and in allotment gardens for the recovery of that part of wastes that can not be utilized for compost preparation. This process is most typical during the autumn season and to a lesser degree during spring. Burning occurs usually in bon fires. Burning modes differ depending on the volume of material burnt, the waste moisture content, the weather conditions, etc. During this process part of domestic wastes (polluted wood, paper, chipboard, films, plastics, etc.) are burned also. Investigations included the collection and preparation of combustible material, the simulation of open burning processes, particulate and gas emission sampling, chemical analysis of sample and data processing. Sampling procedures and sample preparation were agreeable to the emission sampling standards. The aerosol and vapour phases of POPs were collected by ordinary sampling train with pumping of waste gases through filter and solid sorbent (polyurethane foam). For the measurements of PAH in emission, gas chromatography and mass spectrometry were used which make it possible to identify and determine 16 PAH compounds in the samples; this method was used for HCB determination also. Gas chromatography with ECD detector was used for PCB measurement. It was detected that the levels of PAH emission from wastes uncontrolled burning of wastes vary greatly. Influencing factors are composition and properties of refuse, temperature and mode of burning, level air supply. Generally, the increase of content of wood leads to the increase of PAH in emission. PAH emission also increased with increasing temperature of burning. The highest PAH values are characteristic of emissions from domestic refuse burning. Practically, all naphthalene, acenaphthylene, acenaphthene (from 60% to 100% of their total mass) and fluorene (14%-99%) were emitted in gaseous form.

关 键 词:POPs  燃烧法  废物  环境污染  污染控制

Open burning of wastes as the source of environmental contamination by POPs
Sergey V. Kakareka Tamar I. Kukharchyk.Open burning of wastes as the source of environmental contamination by POPs[J].Chinese Journal of Geochemistry,2006,25(B08):177-178.
Abstract:
Keywords:POPs  open burning  wastes  emission  environment
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