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水库现代沉积过程沉积磷的早期成岩作用模型研究
引用本文:朱俊,王雨春,万国江,刘丛强.水库现代沉积过程沉积磷的早期成岩作用模型研究[J].矿物学报,2006,26(3):296-302.
作者姓名:朱俊  王雨春  万国江  刘丛强
作者单位:1. 中国科学院,地球化学研究所,环境地球化学国家重点实验室,贵州,贵阳,550002
2. 中国水利水电科学研究院,水环境研究所,北京,100038;水利部水资源与水生态工程研究中心,北京,100038
摘    要:在沉积磷形态分析、孔隙水化学、核素计年以及吸附解吸实验等的基础上,运用一维“反应-平流-扩散”模型,研究了红枫湖现代沉积过程中磷的沉积改造。结果表明:红枫湖现代沉积过程中,有机态磷的矿化分解和铁结合态磷的络合/溶解,是控制沉积物磷迁移转化动力学的主要机制。沉积物-水界面附近有机磷的快速降解,可能克服沉积界面上铁氧化物对溶解磷的吸附缓冲,而形成向水体的磷酸盐迁移通量;自生磷灰石的沉积改造相对不明显,沉积磷向稳定形态含磷矿物(钙氟磷灰石)的转化过程同样不能影响红枫湖现代沉积过程中磷转化的质量平衡。

关 键 词:沉积磷  早期成岩作用模型  红枫湖水库
文章编号:1000-4734(2006)03-0296-07
收稿时间:2005-12-27
修稿时间:2005年12月27

EARLY DIAGENESIS MODEL OF SEDIMENTARY PHOSPHORUS IN A RESERVOIR
ZHU Jun,WANG Yu-chun,WAN Guo-jiang,LIU Cong-qiang.EARLY DIAGENESIS MODEL OF SEDIMENTARY PHOSPHORUS IN A RESERVOIR[J].Acta Mineralogica Sinica,2006,26(3):296-302.
Authors:ZHU Jun  WANG Yu-chun  WAN Guo-jiang  LIU Cong-qiang
Institution:1. State Key Lab. of Environment Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China; 2. China Institute of Water Resources and Hydroelectric Power Research, Beijing 100038, China
Abstract:To shed more quantitative insight into the redistribution of sedimentary P with depth,based on the data from pore water analysis,solid phase P analysis,sedimentary nuclide chronology and sorption experiment,a mathematical model describing the sedimentary P cycle was applied.The result of this study indicated that the mineralization of organic P and the dissolution of Fe-bound P are the major mechanisms by which the sedimentary P dynamics was controlled during the burial processes of sediments in Hongfeng Lake.The model calculation also showed that the amount of dissolved phosphate provided by organic P mineralization in the surface sediment zone was larger than that absorbed by ferriferous oxide,as a result,there is a potential upward flux of phosphate from sediments to overlying waters.Meanwhile,the result of the model calculation suggested that the processes of authigenic P formation and carbonate fluorapatite are of no significance in mass balance of sedimentary P during the early diagenesis of sediments in Hongfeng Lake.
Keywords:sedimentary phosphorus  early diagenetic mathematical model  reservoir
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