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富砷钒锌铅矿在贵州横塘的发现与研究
引用本文:顾尚义,万国江,毛健全,张启厚.富砷钒锌铅矿在贵州横塘的发现与研究[J].矿物学报,2002,22(1):15-18.
作者姓名:顾尚义  万国江  毛健全  张启厚
作者单位:1. 中国科学院,地球化学研究所,环境地球化学国家重点实验室,贵州,贵阳,550002;贵州工业大学,资源与环境学院,贵州,贵阳,550003
2. 中国科学院,地球化学研究所,环境地球化学国家重点实验室,贵州,贵阳,550002
3. 贵州工业大学,资源与环境学院,贵州,贵阳,550003
基金项目:贵州省八五重点攻关项目
摘    要:水城黄塘发现的钒锌铅矿是迄今为止国内外已知的最富砷的钒锌铅矿,其中As2O3含量高达5.81%,属于钒锌铅矿与砷名矿的类同质同象系列。本文研究了它的产状、化学组成、X-射线衍射特征、红外光谱和稀土元素组成特征并与国外相似矿物进行了对比。结果表明,As在矿物中替代V进行矿物晶格,是原来的铅锌硫化物在表生条件经次生氧化形成,但V和As的富集机制还有待于进一步研究。

关 键 词:砷矾锌铅矿  砷锌铅矿床  表生条件  富集机制  贵州
文章编号:1000-4734(2002)01-0015-04
修稿时间:2001年8月22日

DISCOVERY AND STUDY OF DESCLOIZITE ENRICHED IN ARSENIC IN HENGTANG, GUIZHOU PROVINCE, CHINA
Gu Shangyi , Wan Guojiang Mao Jianquan Zhang Qihou.DISCOVERY AND STUDY OF DESCLOIZITE ENRICHED IN ARSENIC IN HENGTANG, GUIZHOU PROVINCE, CHINA[J].Acta Mineralogica Sinica,2002,22(1):15-18.
Authors:Gu Shangyi  Wan Guojiang Mao Jianquan Zhang Qihou
Institution:Gu Shangyi 1,2 Wan Guojiang 1 Mao Jianquan 2 Zhang Qihou 2
Abstract:Descloizite found in Hengtang of Guizhou Province is characterized by independent occurrence. The mineral is most enriched in arsenic all over the world with the highest As 2O 3 content of 5.81% , belonging to the isomorphous series between descloizite and arsendescloizite. The authors studied the occurrence, chemical composition, XRD characters, IR spectra and REE composition of the mineral and made comparisons with those from other locations in the world. It is concluded that arsenic in the mineral substituted vanadium and found its way into crystal lattice. The descloizite was formed by oxidization of lead and zinc sulfides under supergene conditions. However, further research is necessary for the mechanism of arsenic and vanadium enrichment.
Keywords:descloizite  arsendescloizite  Hengtang
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