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山东昌乐蓝宝石的EPR谱研究
引用本文:陈道前,潘兆橹.山东昌乐蓝宝石的EPR谱研究[J].矿物学报,1997,17(2):215-219.
作者姓名:陈道前  潘兆橹
作者单位:西南工学院资源系!四川绵阳,621002,中国地质大学!湖北武汉,430074
摘    要:本文较详细地分析论述了山东昌乐蓝宝石EPR谱各共振吸收带的位置、强度及其随EAC轴角度变化规律等特征,对各吸收带的归属也进行了深入讨论。通过EPR谱分析,笔者认为山东昌乐蓝宝石中Fe3 是大量存在的,并有可能是Fe的主要存在形式,由此指出,在昌乐蓝宝石改色工艺中过于看重将Fe2 转变为Fe3 将导致蓝宝石灰色成分增加。

关 键 词:蓝宝石  顺磁共振  吸收带  山东昌乐

EPR SPECTRA OF SAPPHIRES FROM CHANGLE,SHANDONG
Chen Daoqina, Pan Zhaolu.EPR SPECTRA OF SAPPHIRES FROM CHANGLE,SHANDONG[J].Acta Mineralogica Sinica,1997,17(2):215-219.
Authors:Chen Daoqina  Pan Zhaolu
Abstract:The EPR spectra of natural sapphires from Changle,Shandong are reported in this paper.The position and intensity-changing and formation of each absorption band are discussed in detail-The hue of sapphires is due to Fe2 /Ti4 charge transfer so that much research has been done onFe2 than Fe3 . It is mostly accepted that most of the Fe ions are present as Fe' , but the EPRsPectra show that Fe3 may be the main form of the total Fe in the sapphires. This conclusion canhelp us to choose a better enhancement for the sapphires from Changle, Shandong.
Keywords:sapphire  paramagnetic resonance  absorption band  Changle Shandong
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