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胶磷矿晶体结构研究
引用本文:黄小芬,张覃.胶磷矿晶体结构研究[J].矿物学报,2011,31(3):566-570.
作者姓名:黄小芬  张覃
作者单位:贵州大学矿业学院,贵州贵阳550003/贵州省非金属矿产资源综合利用重点实验室,贵州贵阳550003
基金项目:国家自然科学基金(批准号:50864003)
摘    要:详细叙述了磷灰石的晶体结构,并采用多种方法对磷灰石结构中配位多面体各元素间的化学键力进行计算,分析了磷灰石的表面特性。针对贵州典型磷矿区具有代表性的胶磷矿试样,其主要由微晶磷灰石组成,采用x射线衍射分析了胶磷矿试样的物相组成、结晶度、晶胞参数以及磷灰石晶粒大小。在扫描电子显微镜下,2种胶磷矿多呈集合体形态,两种胶磷矿中磷酸盐矿物主要为氟磷灰石。

关 键 词:磷灰石  胶磷矿  晶体结构  x射线衍射  扫描电子显微镜

A Study on Crystal Structure of Collophanite
HUANG Xiao-fen,ZHANG Qin.A Study on Crystal Structure of Collophanite[J].Acta Mineralogica Sinica,2011,31(3):566-570.
Authors:HUANG Xiao-fen    ZHANG Qin
Institution:HUANG Xiao-fen1,2,ZHANG Qin1,2(1.Mining College,Guizhou University,Guiyang 550003,China,2.Guizhou Key Laboratory of Comprehensive Utilization of Non-metallic Mineral Resources,China)
Abstract:Crystal chemistry and chemical bonding calculation of apatite structure were summarized in this paper.The collophanite consists chiefly of microcrystalline apatite.The X-Ray diffraction was applied to analysis the phase,crystallinity,unit cell parameters and crystal size of collophanite.Results of scanning electron micrography with energy dispersive spectrometry show that the main mineral is fluorapatite.
Keywords:phosphate ore  collophanite  crystal structure  X-Ray diffraction  scanning electron micrography  
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