Labile barite contents and dissolved barium concentrations on Blake Ridge: New perspectives on barium cycling above gas hydrate systems |
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| Authors: | GT Snyder GR Dickens DG Castellini |
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| Institution: | aDepartment of Earth Sciences, Rice University, Houston, TX 77005, USA |
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| Abstract: | Blake Ridge hosts an extensive gas hydrate system where escaping CH4 is consumed through anaerobic oxidation of methane (AOM) at a sulfate–methane transition (SMT) in shallow sediment. Previous geochemical work on ridge crest sediment has documented Ba fronts above the SMT, and has suggested that these horizons can be used to constrain the evolution of the SMT and AOM over time. We expand on this concept and further test it by determining the labile Ba contents of sediment and the dissolved Ba2+ concentrations of pore waters at four ODP sites on Blake Ridge (on the crest at Sites 994, 995 and 997, and on the southern flank at Site 1059). Labile Ba contents are fairly low at all four sites (0.44 and 1.32 mmol/kg), except within 3 m above the SMT at Sites 994, 995 and 997, where they typically exceed 1.24 mmol/kg and can reach 11.3 mmol/kg. These Ba fronts have a diagenetic origin, and SEM analyses show them to be composed of microcrystalline barite. Site 1059 lacks a prominent Ba front. The lowest labile Ba contents generally underlie the Ba fronts and correlate to the base of the SMT. Dissolved Ba2+ concentrations are low (< 1–4 μM) from the seafloor to within 2 m above the main Ba front. Below this depth, they rapidly increase at Sites 994, 995, and 1059, reaching peak concentrations (to 57 μM) at the base of the SMT. By contrast, a rapid rise in dissolved Ba2+ is not observed at Site 997. Dissolved Ba2+ concentrations are only moderately high (10–25 μM) below the SMT at all four sites. Collectively, this information supports a diagenetic model where barite passing into the SMT dissolves, and some of the dissolved Ba2+ then migrates up to form an authigenic barite peak. The contrasting signatures at the different sites indicate non-steady-state differences in the overall process. The size of the peaks on the crest of Blake Ridge necessitates that the recycling of Ba across the SMT has been operating at the current sub-bottom depths for > 100 kyr. Thus, CH4 escaping through the AOM has likely been fairly constant over this time. It is possible that the SMT is currently rising toward the seafloor at Site 1059. |
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| Keywords: | Barium Methane Gas hydrate Barite Anaerobic methane oxidation Diagenetic fronts |
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