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Geochemistry of basal Cambrian black shales and cherts from the Northern Tarim Basin,Northwest China: Implications for depositional setting and tectonic history
Authors:Bingsong Yu  Hailiang Dong  Elisabeth Widom  Jianqiang Chen  Changsong Lin
Institution:1. Institute of Isotope Hydrology, School of Earth Sciences and Engineering, Hohai University, Nanjing 210098, PR China;2. State Key Laboratory of Geological Processes and Mineral Resources, Faculty of Earth Resources, China University of Geosciences, Wuhan 430074, PR China;3. State Key Laboratory for Mineral Deposits Research, Department of Earth Sciences, Nanjing University, Nanjing 210093, PR China;4. Tarim Oilfield Company Exploration & Development Research Institute, Kuerle 841000, Xinjiang Province, PR China;1. Petroleum Exploration & Production Research Institute, SINOPEC, Beijing 100083, China;2. Department of Geology and Environmental Sciences, State University of New York - Fredonia, Fredonia, NY 14063, USA;3. State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum, Beijing 102249, China;4. Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education, China University of Geosciences, Wuhan 430074, China;1. Department of Earth Sciences, China University of Geosciences, Wuhan 430074, China;2. Chinese Academy of Geological Sciences, Beijing 100037, China;3. Sedimentary Geology Research, Chengdu Center of China Geological Survey, Chengdu 610081, China;4. Applied Research in Ichnology and Sedimentology (ARISE) Group, Department of Earth Sciences, Simon Fraser University, Burnaby V5A 1S6, Canada;5. School of Earth Science, Zhejiang University, Zhejiang 310027, China;6. State Key Laboratory of Biogeology and Environmental Geology, School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China
Abstract:Black shales and thin-bedded cherts in the basal Cambrian are widespread worldwide and they carry important information on the formation of sedimentary basins and on the tectonic history. We studied the geochemical signatures of the early Cambrian black shales and bedded cherts from the Northern Tarim Basin, China, with the objectives of understanding the depositional setting of these rocks and inferring the tectonic history in the region. Twenty two black shales, ten cherts, and two nodular phosphorites were collected from two outcrops at Xiaoerbulake and Sugaitebulake in the Northern Tarim Basin, spanning vertical sections of 8.8 and 7.5 m, respectively. A suite of techniques, including field investigations, X-ray diffraction, electron microscopy, trace element, rare earth element (REE), and isotope geochemistry, were employed to characterize the geochemical signatures of these rocks. Field evidence indicates that the black shales and bedded cherts are over- and underlain by dolomites, suggesting a shallow marine depositional environment. Mineralogical and trace element data suggest that the Tarim black shales and cherts were deposited in a suboxic continental shelf environment, and hydrothermal activity may have extracted certain trace elements from mafic continental crust and concentrated them in the sedimentary basin. REE characteristics for the cherts are very similar to those that are known to be deposited in pelagic ocean floor settings, suggesting that the hydrothermal fluids may be derived from the infant southern Tianshan Ocean in the north of the Tarim Basin. Os isotope signatures at the time of deposition (187Os/188Osi = 1.1–2.7) are typical of crustal signatures, and the radiogenic Os isotope signatures rule out the mantle as a possible source of Os and other metals. A positive correlation between 187Os/188Os and εNd is consistent with upper crust-derived basin sediments that contain a variable contribution of hydrothermal fluids possibly derived from ancient mafic continental crust. These trace element, REE, and isotope systematics collectively suggest that incorporation of hydrothermal fluids derived from ancient, mafic continental crust combined with deposition in relatively reducing conditions may have controlled the chemical and isotopic compositions of these rocks. We infer that the hydrothermal fluid was carried to the continental shelf by upwelling during the initial stages of formation of the southern Tianshan Ocean, where the fluid interacted with thinned, mafic crustal basement lithologies and was subsequently incorporated into the black shales and bedded cherts in the Northern Tarim Basin. This study provides important geochemical evidence for the creation of the Tianshan Ocean, which is a result of break-up of the Rodinia Supercontinent during the early Cambrian.
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