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Synthesis of cordierite using industrial waste fly ash
Authors:Hanaa Hajjou  Latifa Saâdi  Mohamed Waqif
Institution:1.Nanostructures and Condensed Materials Laboratory (LMCN), Faculty of Science and Technology,Marrakech,Morocco
Abstract:Fly ash is a product arising from coal combustion in thermal power plants. It represents a major source of environmental pollution. It is well known by its chemical composition rich of SiO2 and Al2O3. With the aim of preserving the environment against this contamination, fly ash was used along with the starting materials for producing glass cordierite (2MgO, 2Al2O3, 5SiO2). Four formulations were developed by mixing the silica gel, magnesium chloride (MgCl2.6H2O) and fly ash in the percentages enclosing the stoichiometry of cordierite (2MgO, 2Al2O3, 5SiO2). Different experimental techniques (DTA/TGA, X-ray diffraction, FTIR and SEM) were used to characterise the prepared formulations. The results shown that for all formulations, a cordierite phase was obtained at 1200 °C along with several secondary phases such as mullite, cristobalite, silicon oxide, enstatite and spinel. At 1300 °C, pure indialite (α-cordierite) was obtained along with a small amount of spinel. The four formulations sintered at 1200 °C exhibit a homogenous morphology and high porosity. The acicular-shaped indialite grains were observed in both formulations with excess of alumina and excess of magnesia.
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