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兰州市取暖期可吸入颗粒物中单颗粒矿物组成特征
引用本文:肖正辉,邵龙义,孙珍全,张宁,李卫军.兰州市取暖期可吸入颗粒物中单颗粒矿物组成特征[J].矿物岩石地球化学通报,2007,26(1):64-69.
作者姓名:肖正辉  邵龙义  孙珍全  张宁  李卫军
作者单位:1. 中国矿业大学,资源与地球科学系,资源与安全开采国家重点实验室,北京,100083
2. 甘肃省环境监测中心站,兰州,730030
基金项目:国家自然基金资助项目(40575065),新世纪优秀人才支持计划资助项目
摘    要:为研究兰州市2005年冬季大气可吸入颗粒物(PM10)中单颗粒的矿物组成,用能谱扫描电镜识别和统计了兰州市区(东方红广场)和郊区(榆中县)两个采样点的单矿物颗粒。结果在市区样品中识别出方解石、伊/蒙混层、石英、斜长石、伊利石、石膏、绿泥石、高岭石、浊沸石和钾长石等21种矿物,前7种占统计总量的75%以上;郊区样品中识别出20种矿物,以方解石、石英、伊利石、绿泥石、斜长石和伊/蒙混层为主(占70%以上),与市区相比缺少钾石膏、金红石和水铝酸钙而增加了硫酸镁和磷灰石。总体来看,大气PM10中的矿物颗粒可分为粘土类、长石类、碳酸盐类、硫酸盐类、氧化物类和其他六类,以粘土类和碳酸盐类矿物为主(约占60%);冬季市区颗粒物表面的“硫化”现象较郊区严重;这些矿物颗粒主要来自地表土,人为排放和大气中二次化学反应生成的矿物的贡献较小。

关 键 词:兰州市  可吸入颗粒物(PM10)  单矿物颗粒  能谱扫描电镜(SEM/EDX)
文章编号:1007-2802(2007)01-0064-06
修稿时间:2006-06-012006-08-01

Mineral Compositions of Individual Particles in the Inhalable Particulate Matter in the Lanzhou Air during Heating Period
XIAO Zheng-hui,SHAO Long-yi,SUN Zhen-quan,ZHANG Ning,LI Wei-jun.Mineral Compositions of Individual Particles in the Inhalable Particulate Matter in the Lanzhou Air during Heating Period[J].Bulletin of Mineralogy Petrology and Geochemistry,2007,26(1):64-69.
Authors:XIAO Zheng-hui  SHAO Long-yi  SUN Zhen-quan  ZHANG Ning  LI Wei-jun
Institution:1. National Key Laboratory of Coal Resources and Safe Mining and the Department of Resources and Earth Sciences, China University of Mining and Technology, Beijing 100083, China; 2. Central Station of Environmental Monitoring of Gansu Province , Lanzhou 730030, China
Abstract:SEM/EDX is applied to investigate mineral compositions of the individual particles in the inhalable particulate matter(PM10) collected in Lanzhou urban area(Dongfanghong square) and suburb(Yuzhong County) in the winter,2005.The results show that there are 21 types of minerals,in the urban samples including calcite,illite and smectite mixed layers,quartz,plagioclase,illite,gypsum,chlorite,kaolinite,laumontite,K-feldspar,with the dominant(over 75%) minerals being calcite,illite/smectite,chlorite,quartz,plagioclase,illite,gypsum and chlorite.There are 20 types of minerals in the suburban samples,with the dominant(over 70%) minerals being calcite,quartz,illite,chlorite,plagioclase and illite/smectite.Comparing with the samples collected in urban area,the samples collected in suburb contain no syngenite,rutile and calcium aluminate but magnesium sulfate and apatite.These minerals belong to clay,feldspar,carbonate,sulphate,oxide minerals,with dominant minerals of clay and carbonate.It is indicated that the surface of particles in urban area was more seriously sulfurated than that of the particles in suburb in winter.The inhalable particles in the urban area and suburb were originated mainly from soil-derived dust.
Keywords:Lanzhou  inhalable particulate matter(PM10)  individual particles  SEM/EDX
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