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Long chain alkyl heteroaromatics in coal identified by tandem mass spectrometry
Authors:Karl V Wood  R Graham Cooks  Zifambi Mudamburi  Peter H Given
Institution:1. Engine/Fuels Laboratory, Institute for Interdisciplinary Engineering Studies, Purdue University, West Lafayette, IN 47907, U.S.A.;2. Department of Chemistry, Purdue University, West Lafayette, IN 47907, U.S.A.;3. College of Earth and Mineral Sciences, Pennsylvania State University, University Park, PA 16802, U.S.A.
Abstract:The presence of a series of long chain alkyl aromatic and heteroaromatic hydrocarbons was confirmed in a Utah boghead coal using tandem mass spectrometry. Parent and neutral loss scans were utilized to characterize the complex mixture and daughter scans were used to identify individual components.
Keywords:mass spectrometry/mass spectrometry  coal liquids  alkylnaphthalenes  alkylpyridinols  tandem mass spectrometry  neutral loss spectrum  parent spectrum  daughter spectrum
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