Reconstruction of floral changes during deposition of the Miocene Embalut coal from Kutai Basin,Mahakam Delta,East Kalimantan,Indonesia by use of aromatic hydrocarbon composition and stable carbon isotope ratios of organic matter |
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| Authors: | Sri Widodo Achim Bechtel Komang Anggayana Wilhelm Püttmann |
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| Institution: | 1. Institute of Atmospheric and Environmental Sciences, Department of Analytical Environmental Chemistry, J.W. Goethe University, Altenhöferallee 1, D-60438 Frankfurt a.M., Germany;2. EAWAG, Department of Surface Waters – Biogeochemistry, Seestr. 79, CH-6047 Kastanienbaum, Switzerland;3. Department of Mining Engineering, Bandung Institute of Technology, Jln Ganesa 10, I-40132 Bandung, Indonesia |
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| Abstract: | The distribution of aromatic hydrocarbons and stable carbon isotope ratios of organic matter in a series of nine Miocene Embalut coal samples obtained from nine coal seams of Kutai Basin, East Kalimantan, Indonesia were studied. The rank of the Embalut coals ranged from lignites to low rank sub-bituminous coals (0.36–0.50% Rr), based on measurements of huminite reflectance. The aromatic hydrocarbon fractions of all coal samples were dominated by cadalene in the lower boiling point range and picene derivatives in the higher boiling point range of the gas chromatograms. Cadalene can be attributed to the contribution of Dipterocarpaceae and various hydrated picenes to the contribution of additional angiosperms to the coal forming vegetation. The picenes originate from alpha- and beta-amyrin. However, in some coal samples minor amounts of simonellite and retene were also detected which argues for an additional contribution of gymnosperms (conifers) to coal forming vegetation preferentially in the Middle Miocene and at the beginning of the Late Miocene. The results of stable carbon isotope ratios (δ13C) in most of the coal samples are consistent with their origin from angiosperms (δ13C between ?27.0‰ and ?28.0‰). During the Miocene the climate of Mahakam Delta was not uniformly moist and cooler than the present day climate. This would have been favourable for the growth of conifers, especially in the montane forests. The contribution of conifers to the Embalut coals might be a result of the cool Middle/Late Miocene climate during peat accumulation in the Kutai Basin. |
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