| 有机—铜配合物热稳定性及热分解产物的实验研究 |
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| 引用本文： | 庄汉平,冉崇英.有机—铜配合物热稳定性及热分解产物的实验研究[J].现代地质,1996,10(3):408-413. |
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| 作者姓名： | 庄汉平 冉崇英 |
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| 作者单位： | Zhuang Hanping 1) Ran Chongying 2) Lu Jialan 3) 1) Institute of Geochemistry，Academy of Chinese Sciences，Guiyang，550002; 2) Department of Geology，Kunming Institute of Technology，Kunming，650093); 3) Guangzhou Institute of Geochemistry，A |
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| 摘 要： | 通过实验研究了富里酸、氨基丙酸和半胱氨酸３种有机质与铜的配合物的热稳定性及热分解产物特征。结果表明：富里酸—铜配合物在１９０～２００℃时缩合成类干酪根物质，被富里酸配合的铜一同进入到该物质中去；氨基丙酸—铜配合物在１４０～１５０℃分解，形成π键配合物“二（三）氯·（乙炔）合铜（Ⅰ）”；半胱氨酸—铜配合物很不稳定，８０℃便开始分解，生成黑色沉淀物“二水合四氯合铜酸铵”，而没有生成铜的金属硫化物
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| 关 键 词： | 有机－铜配合物 热稳定性热分解产物 实验研究 |
EXPERIMENTAL STUDIES ON THERMAL STABILITIES AND DECOMPOSING PRODUCTS OF ORGANIC COPPER COMPLEXES |
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| Zhuang Hanping Ran Chongying Lu Jialan Institute of Geochemistry,Academy of Chinese Sciences,Guiyang,.EXPERIMENTAL STUDIES ON THERMAL STABILITIES AND DECOMPOSING PRODUCTS OF ORGANIC COPPER COMPLEXES[J].Geoscience——Journal of Graduate School,China University of Geosciences,1996,10(3):408-413. |
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| Authors: | Zhuang Hanping Ran Chongying Lu Jialan Institute of Geochemistry Academy of Chinese Sciences Guiyang |
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| Institution: | Zhuang Hanping 1) Ran Chongying 2) Lu Jialan 3) 1) Institute of Geochemistry,Academy of Chinese Sciences,Guiyang,550002, 2) Department of Geology,Kunming Institute of Technology,Kunming,650093), 3) Guangzhou Institute of Geochemistry,A |
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| Abstract: | In this paper, we report the experimental results on thermal stabilities and decomposing product characteristics of organic copper complexes. The results state that (1) the complex of fulvic acid (FA) and copper condensates and forms kerogen like material at 190￣200℃ and copper complexing with FA possibly enters into that material during the process; (2) alanine copper complex decomposes and forms π bonding organic metal compound C 2H 2Cl x Cu x(x =2￣3) copper(I) chloride acteylene at the temperature of 140￣150℃; (3) cysteine copper complex is thermal instability and decomposes even at 80℃, and the thermal decomposing product is black floccule (NH 4) 2CuCl 4·2H 2O(ammonium copper chloride hydrate) rather than metallic sulfide of copper. |
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| Keywords: | organic copper complex thermal stability thermal decomposing product experimental study |
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