| 松辽盆地北部中二叠统碳酸盐岩元素和稳定同位素地球化学特征与古环境 |
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| 引用本文： | 黄清华,席党鹏,王辉,张文婧,王建伟,曹维福,贾卧,王丽静.松辽盆地北部中二叠统碳酸盐岩元素和稳定同位素地球化学特征与古环境[J].现代地质,2021,35(5):1282-1295. |
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| 作者姓名： | 黄清华 席党鹏 王辉 张文婧 王建伟 曹维福 贾卧 王丽静 |
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| 作者单位： | 1.大庆油田有限责任公司勘探开发研究院,黑龙江 大庆 1637122.中国地质大学(北京) 地球科学与资源学院,北京 1000833.大庆油田有限责任公司第二采油厂,黑龙江 大庆 163414 |
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| 基金项目： | 国家自然科学基金项目“松辽盆地与辽西地区早白垩世古湖泊环境演化”(41790452);国家重点研发计划项目(2019YFC0605403);中国石油天然气股份有限公司重大专项课题“松北深层天然气富集规律、勘探技术研究与规模增储”(2016E-0203) |
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| 摘 要： | 松辽盆地中二叠统哲斯组发育一套暗色泥岩、灰色砂砾岩与灰岩沉积组合,灰岩中产海相腕足类和双壳类化石。由于受钻井进尺和取心资料限制,前人对盆地覆盖区晚古生代地层及其沉积环境研究较少。对采自松辽盆地杜101井、杜103井剖面哲斯组的白云质灰岩进行了系统的稳定同位素和微量元素、稀土元素分析,首次获取了盆地覆盖区中二叠统灰岩元素地球化学资料。测试结果显示碳同位素δ13CPDB值一般>0(均值为1.68‰),氧同位素δ18OPDB值全部<-15‰(均值为-19.98‰),碳、氧稳定同位素关系图解显示二者呈正相关关系,表明白云岩化作用对灰岩同位素改造作用明显。稀土元素(REE+Y)总量为56.88×10-6~143.72×10-6,均值为108.92×10-6,PAAS标准化后显示具有轻稀土相对于中稀土和重稀土亏损、δEu(均值0.94,最大值1.57)负异常、δCe(均值0.87,最大值1.06)普遍负异常和相对高的Y/Ho均值(均值34.59)等特点,与正常海相具有大体相同的稀土元素配分模式;而微量元素Ba(均值281.55×10-6)、Zn(均值71.91×10-6)、Y(均值17.44×10-6)、Zr(均值117.75×10-6)和Rb(均值66.84×10-6)等元素含量整体较高,Sr/Ba(均值2.91)、Th/U(均值2.75)、V/Cr(均值1.45)和V/(V+Ni)(均值0.66)等比值适中,指示研究区哲斯组沉积时期主体为一种频繁受陆源碎屑混染作用影响的碳酸盐台地或滨海岸环境。
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| 关 键 词： | 元素地球化学特征 白云质灰岩 碳酸盐台地或滨海岸环境 中二叠统哲斯组 松辽盆地 |
| 收稿时间： | 2020-07-12 |
| 修稿时间： | 2021-04-21 |
Element and Isotope Geochemical Characteristics of Middle Permian Carbonates and Paleoenvironment in the Northern Songliao Basin |
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| HUANG Qinghua,XI Dangpeng,WANG Hui,ZHANG Wenjing,WANG Jianwei,CAO Weifu,JIA Wo,WANG Lijing.Element and Isotope Geochemical Characteristics of Middle Permian Carbonates and Paleoenvironment in the Northern Songliao Basin[J].Geoscience——Journal of Graduate School,China University of Geosciences,2021,35(5):1282-1295. |
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| Authors: | HUANG Qinghua XI Dangpeng WANG Hui ZHANG Wenjing WANG Jianwei CAO Weifu JIA Wo WANG Lijing |
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| Institution: | 1. Exploration and Development Research Institute of Daqing Oilfield Co. Ltd.,Daqing,Heilongjiang 163712,China2. School of Earth Sciences and Resources,China University of Geosciences,Beijing 100083,China3. No.2 Oil Production Plant of Daqing oilfield Co.Ltd.,Daqing,Heilongjiang 163414, China |
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| Abstract: | The Middle Permian Zhesi Formation comprises a suite of dark mudstone, gray sandstone, and carbonate in the Songliao Basin, of which the limestone contains marine brachiopod and bivalve fossils. Limited by drilling footage and core data, few previous studies were conducted on the upper Paleozoic strata and sedimentary environment of the basin. Compositions of trace elements (incl. rare earth elements (REEs)) and carbon-oxygen isotopes were measured on the Zhesi Formation dolomitic limestone in the well D101 and D103, and we first presented the element geochemical data of these Middle Permian limestone in the basin. The results show that the δ13CPDB values are generally >0 (mean 1.68‰) and δ18OPDB values < -15‰ (mean -19.98‰), the carbon-oxygen isotope plot indicates positive correlation between the two isotopes, which suggests that dolomitization has obvious effect on the isotopic transformation of limestone. Total $\sum$REE+Y contents of the dolomitic limestone range from 56.88×10-6 to 143.72×10-6 (mean 108.92×10-6). Compared with MREE and HREE, PAAS-normalized LREE depletion was observed with no or negative δEu anomalies (mean 0.94, max 1.57). Negative Ce anomalies are common (mean δCe 0.87, max 1.06). The samples have relatively high Y/Ho ratios (mean 34.59), and the same REE distribution pattern as normal marine facies. The mean trace element contents are relatively high in general, such as Ba (281.55×10-6), Zn (71.91×10-6), Y (17.44×10-6), Zr (117.75×10-6) and Rb (66.84×10-6), and the samples have medium mean ratios of Sr/Ba (2.91), Th/U (2.75), V/Cr (1.45), V/(V+Ni) (0.66). We concluded that the region was a carbonate platform or coastal environment affected by terrigenous debris in the Middle Permian. |
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| Keywords: | geochemical feature dolomitic limestone carbonate platform coastal environment Middle Permian Zhesi Formation Songliao Basin |
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