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Nanoparticles of noble metals in the supergene zone |
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| Authors: | S M Zhmodik Yu A Kalinin N A Roslyakov A G Mironov Yu L Mikhlin D K Belyanin N A Nemirovskaya A M Spiridonov G V Nesterenko E V Airiyants T N Moroz T A Bul’bak |
| Institution: | 1. Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, pr. Akademika Koptyuga 3, Novosibirsk, 630090, Russia 2. Geological Institute, Siberian Branch, Russian Academy of Sciences, ul. Sakh??yanovoi 6a, Ulan-Ude, 670047, Russia 3. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, ul. Karla Marksa 42, Krasnoyarsk, 660049, Russia 4. Institute of Geochemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1a, Irkutsk, 664033, Russia |
| Abstract: | Formation of noble metal nanoparticles is related to various geological processes in the supergene zone. Dispersed mineral phases appear during weathering of rocks with active participation of microorganisms, formation of soil, in aqueous medium and atmosphere. Invisible gold and other noble metals are incorporated into oxides, hydroxides, and sulfides, as well as in dispersed organic and inorganic carbonic matter. Sulfide minerals that occur in bedrocks and ores unaltered by exogenic processes and in cementation zone are among the main concentrators of noble metal nanoparticles. The ability of gold particles to disaggregate is well-known and creates problems in technological and analytical practice. When Au and PGE nanoparticles and clusters occur, these problems are augmented because of their unusual reactions and physicochemical properties. The studied gold, magnetite, titanomagnetite and pyrite microspherules from cementation zone and clay minerals of laterites in Republic of Guinea widen the knowledge of their abundance and inferred formation conditions, in particular, in the contemporary supergene zone. Morphology and composition of micrometer-sized Au mineral spherules were studied with SEM and laser microprobe. The newly formed segregations of secondary gold on the surface of its residual grains were also an object of investigation. The character of such overgrowths is the most indicative for nanoparticles. The newly formed Au particles provide evidence for redistribution of ultradispersed gold during weathering. There are serious prerequisites to state that microorganisms substantially control unusual nano-sized microspherical morphology of gold particles in the supergene zone. This is supported by experiments indicating active absorption of gold by microorganisms and direct evidence for participation of Ralstonia metallidurans bacteria in the formation of peculiar corroded bacteriomorphic surface of gold grains. In addition, the areas enriched in carbon and nitrogen have been detected with SEM on the surface of gold spherules from Guinea. Such organic compounds as serine, alanine, and glycine are identified on their surface with Raman spectroscopy. The experiments have been carried out and new data have been obtained indicating the role of micromycetes in concentration and distribution of noble metals in ferromanganese nodules of the World Ocean. Au and Pt were detected in the system with radioisotopes. It has been established that two forms of gold distribution develop within pseudomorphs of fungi colonies: (1) as pseudomorphic concentrates and (2) dispersed form unrelated to the colony structure. Inhomogeneities in distribution of dispersed platinum are manifested in the form of linear anomalies with elevated concentrations at the margins of the colonies. |
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