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吐哈盆地丘东次凹低熟气的生成与动力学研究
引用本文:张长春,陶伟,张馨,王晓峰,邹艳荣.吐哈盆地丘东次凹低熟气的生成与动力学研究[J].沉积学报,2008,26(5):857-863.
作者姓名:张长春  陶伟  张馨  王晓峰  邹艳荣
作者单位:中国科学院广州地球化学所有机地球化学国家重点实验室 广州 510640
基金项目:国家重点基础研究发展计划(973计划),国家自然科学基金
摘    要:采用黄金管—高压釜封闭体系,对吐哈盆地艾试1井的泥岩和煤岩进行了低温热解实验。根据实验结果,分别求取了干气(C1)、湿气(C2~C5)生成过程的初始动力学参数,然后将单一活化能的动力学参数进一步优化为具有高斯分布的活化能,优化后的动力学参数能较好拟合实验数据。利用优化后的动力学模型模拟了吐哈盆地丘东凹陷八道湾组天然气早期生成过程,并将模拟结果与实际地质资料进行了对比。结果表明,经过优化后的低温恒温热解动力学,能有效评价早期生气过程;在丘东次陷发现的天然气,与八道湾组源岩关系密切。

关 键 词:热解    天然气    动力学    低熟气    吐哈盆地
收稿时间:1900-01-01

Low Mature Gas Generation and Kinetics in Qiudong Depression,Turpan-Hami Basin
ZHANG Chang-chun,TAO Wei,ZHANG Xin,WANG Xiao-feng,ZOU Yan-rong.Low Mature Gas Generation and Kinetics in Qiudong Depression,Turpan-Hami Basin[J].Acta Sedimentologica Sinica,2008,26(5):857-863.
Authors:ZHANG Chang-chun  TAO Wei  ZHANG Xin  WANG Xiao-feng  ZOU Yan-rong
Institution:The State Key Laboratory of Organic Geochemitry,Guangzhou Institute of Geochemitry,CAS,Guangdong 510640
Abstract:The low temperature pyrolysis for coal and mudstone samples collected from Well AS-1 in Turpan-Hami basin was carried out in the closed system with gold-tube autovlaves.The initial kinetic parameters of dry and wet gases generation are calculated according to the pyrolysis data.Then the kinetic parameters of single activation energy are further optimized into Gaussian distribution of activation energies,which is better to fit empirical data.The optimized kinetic parameters are applied to modeling the early gas generation of Badaowan Formation in Qiudong subsag,Turpan-Hami basin,which shows that the modeling results match well with the geological process of early natural gas generation;the isothermal pyrolysis at low temperature is an effectual way to evaluate the early gas generation;the natural gas discovered in Qiudong subsag is closely associated with the source rocks of the Badaowan Formation.
Keywords:pyrolysis  natural gas  kinetics  low mature gas  Turpan-Hami Basin
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