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黔东北黑色泥岩盆地含锰岩系的铁锰地球化学特征
引用本文:潘文,禚喜准,陈骁帅,杨胜堂,赵爽.黔东北黑色泥岩盆地含锰岩系的铁锰地球化学特征[J].沉积学报,2016,34(5):868-880.
作者姓名:潘文  禚喜准  陈骁帅  杨胜堂  赵爽
作者单位:1.中国地质大学(武汉)地球科学学院 武汉 430074;
基金项目:国家自然科学基金(41402101),中国地质调查区域地质调查项目(121201010000150011-12)National Natural Science Foundation of China
摘    要:黑色泥岩盆地内的菱锰矿矿床中常伴生大量黄铁矿,由于菱锰矿和黄铁矿的沉积过程难以直接观察,铁锰的富集关系尚不明确。为了探讨二者的相互关系,以黔东北西溪堡锰矿的典型剖面为例,根据岩石薄片、TOC分析和元素分析等手段,分析了含锰岩系及其顶底板的岩性序列、矿物组合和铁锰地球化学特征,与现代沉积的菱锰矿进行了对比分析。研究表明,在黄铁矿和菱锰矿富集关系上,西溪堡锰矿与现代波罗的海具有类似特征。含锰岩系顶板和底板的锰含量较低;含锰岩系内部的Mn含量波动很大,与铁含量呈负相关。黄铁矿和菱锰矿的沉淀析出具有先后顺序,通常黄铁矿从溶液中析出在先,菱锰矿沉淀在后。

关 键 词:大塘坡组    菱锰矿    黄铁矿    Mn/Fe比    沉积分异
收稿时间:2015-07-27

Geochemical Characteristics of Manganese Bearing Rock Series in Black Shale Basins of Northeast Guizhou,China
PAN Wen,ZHUO XiZhun,CHEN XiaoShuai,YANG ShengTang,ZHAO Shuang.Geochemical Characteristics of Manganese Bearing Rock Series in Black Shale Basins of Northeast Guizhou,China[J].Acta Sedimentologica Sinica,2016,34(5):868-880.
Authors:PAN Wen  ZHUO XiZhun  CHEN XiaoShuai  YANG ShengTang  ZHAO Shuang
Institution:1.Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074, China;2.Department of Geology, Liaoning Technical University, Fuxin, Liaoning 123000, China;3.No. 103 Geological Survey, Guizhou Bureau of Geology and Mineral Resources, Tongren, Guizhou 554300, China
Abstract:The rhodochrosite ores in black shale basins are usually occupied by a large quantity of pyrites, cause the deposit processes of rhodochrosite and pyrite are hard to observe directly, the enrichment relationship of them is not clear currently. To study the correlation between them, this research selected typical profile of Xixibao manganese ore in northeast of Guizhou province as example. It is based on ordinary thin section, TOC analyses and elemental analyses, which analyzed lithological sequence, mineral assemblage and the geochemical characteristics of Mn and Fe in the manganese-bearing rock series and the roof and floor of them, and at the same time carried out comparison analyses with modern rhodochrosite deposit. Reaearch showed that the Xixibao manganese ore did share some similar characteristics with that of modern Baltics Sea on the enrichment relationship of pyrite and rhodochrosite. The Mn content is low in both roof and floor of the manganese-bearing rock series; inner the manganese-bearing rock series the Mn content fluctuated greatly and is negatively correlated with the Fe content. The precipitation of pyrite and rhodochrosite has a sequence, usually the pyrites are precipitated first from the solution and followed by rhodochrosite.
Keywords:Datangpo Formation  rhodochrosite  pyrite  Mn/Fe ratio  sedimentary differentiation
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