| 松辽盆地庆深气田异常氢同位素组成成因研究 |
| |
| 引用本文： | 刘全有,;戴金星,;金之钧,;李剑,;周庆华,;冯子辉,;孙红军.松辽盆地庆深气田异常氢同位素组成成因研究[J].地球化学,2014(5):460-468. |
| |
| 作者姓名： | 刘全有 ;戴金星 ;金之钧 ;李剑 ;周庆华 ;冯子辉 ;孙红军 |
| |
| 作者单位： | [1]中国石化石油勘探开发研究院,北京100083; [2]中国石油勘探开发研究院,北京100083; [3]中国石油勘探开发研究院廊坊分院,河北廊坊065007; [4]中国石油大庆油田勘探开发研究院,黑龙江大庆163712 |
| |
| 基金项目： | 国家自然科学基金（41322016）;国家重点基础研究发展计划项目（2012cB214800）;中国石油天然气股份有限公司科学研究与技术开发项目（07-01C-01-07） |
| |
| 摘 要： | 对松辽盆地徐家围子断陷庆深气田天然气组分、碳氢同位素和稀有气体同位素的分析表明,天然气以烷烃气为主,烷烃气碳同位素组成随着碳数增加呈变轻趋势,且δ13C1＆gt;-30‰, R/Ra一般大于1.0,δ13CCO2值介于-16.5‰~-5.1‰之间；氢同位素组成δD1=-205‰~-197‰,平均值为-203‰,δD2=-247‰~-160‰,平均值为-195‰,δD3=-237‰~-126‰,平均值为-163‰,且存在氢同位素组成倒转现象,即δD1＆gt;δD2＆lt;δD3。根据对庆深气田天然气不同地球化学特征分析,认为该气田烷烃气中重烃主要为有机成因,而 CH4有相当无机成因混入。庆深气田烷烃气氢同位素组成具有 CH4变化小,而重烃（δD2,δD3）变化大的特点。根据与朝阳沟地区天然气烷烃气氢同位素组成对比分析,认为 CH4主要表现为无机成因,而重烃气（δD2,δD3）主要为有机成因,且无机成因CH4氢同位素组成重于有机成因CH4。
|
| 关 键 词： | 天然气 氢同位素组成 地球化学 庆深气田 |
Abnormal hydrogen isotopes of natural gases from the Qingshen gas field,the Songliao Basin |
| |
| Institution: | LIU Quan-you, DAI Jin-xing, JIN Zhi-jun, LI Jian, ZHOU Qing-hua, FENG Zi-hui, SUN Hong-jun (1.Exploration and Production Research Institute, SINOPEC, Beijing 100083, China; 2.Research Institute of Petroleum Exploration and Development, PetroChina, Beijing 100083, China;3. Langfang Branch of Research Institute of Petroleum Exploration and Development. PetroChina, Langfang 065007, China;4.Daqing Oilfield Company, PetroChina, Daqing 163712, China) |
| |
| Abstract: | By measuring chemical compositions, carbon and hydrogen isotope compositions and noble gas isotopes of natural gases from the Qingshen gas field, Songliao Basin are characterized by a dominant component of alkanes gases, enrichment of 12C with increasing molecular weight, heavyδ13C1 values （δ13C1＆gt;-30‰）, R/Ra＆gt;1.0, andδ13CCO2 values ranging from-16.5‰to-5.1‰. The distributive range of theδD1,δD2,δD3 values for natural gases from the Qingshen gas field are -205‰ to -197‰ （average values = -203‰）, -247‰ to -160‰ （average value=-195‰）,-237‰to -126‰（average value=-163‰） , respectively, associated with a partial reversal of the hydrogen isotopic trend of C1-C3 alkanes, i.e. δD1＆gt; δD2＆lt; δD3. Based on the geochemical parameters of natural gases from the Qingshen gas field, the heavy hydrogen gases were derived from the thermal decomposition of organic matter, whereas partial concentration of methane might be entrapped from the abiogenic alkanes and mixed with thermogenic alkanes. A narrow distribution of methaneδD values and a large range ofδD values of C2 and C3 are observed in the Qingshen gas field. By comparison with the hydrogen isotopic compositions of gaeous alkanes in the Chaoyanggou region, methane in the Qingshen gas field is partially from abiogenic gas, and the heavy hydrocarbon gases （δD2, δD3） are mainly derived from organic matters, with the δD values of abiogenic methane higher than those of thermogenic methane. |
| |
| Keywords: | natural gas hydrogen isotopic composition geochemistry Qingshen gas field |
| 本文献已被 维普 等数据库收录！ |
|
